Palladium(II) and Palladium(II)-Platinum(II) mixed metal complexes with mercapto-1,3,4-thiadiazolate

Bulletin of the Chemical Society of Japan

Volumn 79, Issue 8, 2006, Pages 1223-1230

  Tannai, Hidenori ^a   Tsuge, Kiyoshi ^a   Sasaki, Yoichi ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRONIC SPECTRA; HETEROMETALLIC COMPLEX; LIGANDS; METAL COMPLEXES;

COORDINATION REACTIONS; CRYSTAL STRUCTURE; PALLADIUM; REACTION KINETICS; REDOX REACTIONS;

COMPLEXATION;

2 AMINO 5 MERCAPTO 1,3,4 THIADIAZOLE; 2,5 DIMERCAPTO 1,3,4 THIADIAZOLE; COORDINATION COMPOUND; MERCAPTO 1,3,4 THIADIAZOLATE; METAL COMPLEX; PALLADIUM; PLATINUM; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; OXIDATION REDUCTION REACTION; STRUCTURE ANALYSIS; SYNTHESIS; ULTRAVIOLET SPECTROPHOTOMETRY; X RAY DIFFRACTION;

EID: 33750631754     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.79.1223     Document Type: Article

References (36)

1. a) E. S. Raper, Coord. Chem. Rev. 1985, 61, 115.
2. b) E. S. Raper, Coord. Chem. Rev. 1994, 129, 91.
3. c) E. S. Raper, Coord. Chem. Rev. 1996, 153, 199.
4. d) E. S. Raper, Coord. Chem. Rev. 1997, 165, 475.
5. e) P. D. Akrivos, Coord. Chem. Rev. 2001, 213, 181.
6. P. Mura, B. G. Olby, S. D. Robinson, Inorg. Chim. Acta 1985, 97, 45.
7. M. V. Castaño, M. M. Plasencia, A. Macias, J. S. Casas, J. Sordo, E. E. Castellano, J. Chem. Soc., Dalton Trans. 1989, 1409.
8. J. D. E. T. Wilton-Ely, A. Schier, H. Schmidbaur, Organometallics 2001, 20, 1895.
9. J. D. E. T. Wilton-Ely, A. Schier, N. W. Mitzel, H. Schmidbaur, Inorg. Chem. 2001, 40, 6266.
10. M. V. Castaño, A. Sánchez, J. S. Casas, J. Sordo, E. E. Castellano, Inorg. Chim. Acta 1992, 201, 83.
11. a) C. Ma, F. Li, D. Wang, H. Yin, J. Organomet. Chem. 2003, 667, 5.
12. b) C. Ma, J. Zhang, F. Li, R. Zhang, Eur. J. Inorg. Chem. 2004, 2775.
13. H. Tannai, K. Tsuge, Y. Sasaki, O. Hatozaki, N. Oyama, Dalton Trans. 2003, 2353.
14. H. Tannai, K. Tsuge, Y. Sasaki, Inorg. Chem. 2005, 44, 5206.
15. P. Castan, F. Dahan, S. Wimmer, F. L. Wimmer, J. Chem. Soc., Dalton Trans. 1990, 2679.
16. Crystal Clear, Rigaku Corporation, Tokyo, 1999.
17. teXsan v.1.11, Molecular Structure Corporation, 2000.
18. M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, J. A. Montgomery, Jr., T. Vreven, K. N. Kudin, J. C. Burant, J. M. Millam, S. S. Iyengar, J. Tomasi, V. Barone, B. Mennucci, M. Cossi, G. Scalmani, N. Rega, G. A. Petersson, H. Nakatsuji, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, M. Klene, X. Li, J. E. Knox, H. P. Hratchian, J. B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R. E. Stratmann, O. Yazyev, A. J. Austin, R. Cammi, C. Pomelli, J. W. Ochterski, P. Y. Ayala, K. Morokuma, G. A. Voth, P. Salvador, J. J. Dannenberg, V. G. Zakrzewski, S. Dapprich, A. D. Daniels, M. C. Strain, O. Farkas, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. V. Ortiz, Q. Cui, A. G. Baboul, S. Clifford, J. Cioslowski, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, M. Challacombe, P. M. W. Gill, B. Johnson, W. Chen, M. W. Wong, C. Gonzalez, J. A. Pople, Gaussian 03, revision C.02, Gaussian, Inc., Wallingford, CT, 2004.
19. a) A. D. Becke, J. Chem. Phys. 1993, 98, 5648.
20. b) A. D. Becke, Phys. Rev. A 1988, 38, 3098.
21. c) C. Lee, W. Yang, R. G. Parr, Phys. Rev. B 1988, 37, 785.
22. a) P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 270.
23. b) W. R. Wadt, P. J. Hay, J. Chem. Phys. 1985, 82, 284.
24. c) P. J. Hay, W. R. Wadt, J. Chem. Phys. 1985, 82, 299.
25. a) Z. D. Bugarcic, G. Liehr, R. J. van Eldik, J. Chem. Soc., Dalton Trans. 2002, 951.
26. b) Z. D. Bugarcic, G. Liehr, R. J. van Eldik, J. Chem. Soc., Dalton Trans. 2002, 2825.
27. a) S. Cosar, M. B. L. Janik, M. Flock, E. Freisinger, E. Farkas, B. J. Lippert, J. Chem. Soc., Dalton Trans. 1999, 2329.
28. b) G. M. Intille, C. E. Pfluger, W. A. Baker, Jr., Cyrst. Struct. Commun. 1973, 2, 217.
29. c) Y. Yamada, K. Fujisawa, K. Okamoto, Bull. Chem. Soc. Jpn. 2000, 73, 2297.
30. d) X. Liu, S. L. Renard, C. A. Kilner, M. A. Halcrow, Inorg. Chem. Commun. 2003, 6, 598.
31. e) E. J. MacLean, R. I. Robinson, S. J. Teat, C. Wilson, S. J. Woodward, J. Chem. Soc., Dalton Trans. 2002, 3518.
32. B.-C. Tzeng, A. Schier, H. Schmidbaur, Inorg. Chem. 1999, 38, 3978.
33. a) B.-C. Tzeng, W.-F. Fu, C.-M. Che, H.-Y. Chao, K.-K. Cheung, S.-M. Peng, J. Chem. Soc., Dalton Trans. 1999, 1017.
34. b) M. G. Hill, J. A. Bailey, V. M. Miskowski, H. B. Gray, Inorg. Chem. 1996, 35, 4585.
35. c) J. S. Field, R. J. Haines, D. R. McMillin, G. C. Summerton, J. Chem. Soc., Dalton Trans. 2002, 1369.
36. By TD-DFT calculation, the lowest energy transitions were evaluated as the HOMO-LUMO transitions for both platinum and palladium complexes as expected. The calculated energies and oscillator strengths were 1.29 eV (960 nm) and 0.0180, and 1.34 eV (930 nm) and 0.0094, for platinum and palladium complexes, respectively. ancy of the calculated and observed transition energies may be attributed to that the calculated models are ions in vacuum while the experiments are performed in the solution containing counter cations. The energies of lone pairs are relatively sensitive to the environments such as the molecular geometries, solvents, and counter ions.