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rad is the natural radiative decay lifetime. If we neglect possible electronic interactions between polymer molecules and thus assume that the intrinsic radiative lifetime of the molecule is unchanged by dilution (i.e., changes only occur to the nonradiative decay rate), then changes in the observed decay lifetime are directly proportional to changes in the fluorescence quantum efficiency. We find that the fluorescence decay lifetime of a pure film of F8BT is 1.1 ns, which increases by ca. 60 % to 1.8 ns when it is diluted into a PMMA thin film (at a concentration of 2 % by mass). The decay lifetime of F8 is ca. 320 ps in a pure thin film, which increases by around 6 % to 340 ps when diluted (also at 2 % by mass) into PMMA. This suggests that the fluorescence quantum efficiency of F8BT increases strongly when diluted into PMMA, however the F8 quantum efficiency is much less sensitive to PMMA dilution.
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