Size effects in BaTiO3 nanopowders studied by EPR and NMR

Ferroelectrics

Volumn 316, Issue , 2005, Pages 43-49

  Erdem, E ^a   Boettcher, R ^a   Glaesel, H J ^b   Hartmann, E ^b   Klotzsche, G ^a   Michel, D ^a  

^a UNIVERSITY OF LEIPZIG   (Germany)

^b LEIBNIZ INSTITUTE OF SURFACE ENGINEERING IOM   (Germany)

Author keywords

EPR; Ferroelectricity; Nanoparticles; NMR; Perovskites; Size effects

Indexed keywords

BARIUM TITANATE; FERROELECTRICITY; MEASUREMENT THEORY; NUCLEAR MAGNETIC RESONANCE; PARAMAGNETIC RESONANCE; PARTICLE SIZE ANALYSIS; PEROVSKITE; TENSORS;

QUADRUPOLE COUPLING TENSORS; SIZE EFFECTS; STRUCTURE MODELS;

NANOSTRUCTURED MATERIALS;

EID: 33750441585     PISSN: 00150193     EISSN: 15635112     Source Type: Conference Proceeding    
DOI: 10.1080/00150190590963129     Document Type: Article

References (25)

1. R. E. Newnham and A. Amin, Smart systems: Microphones, fish farming, and beyond - Smart materials, acting as both sensors and actuators, can mimic biological behavior. Chemtech 29, 38-47 (1999).
2. W. Cochran, Crystal stability and the theory of ferroelectricity. Adv. Phys. 9, 387-423 (1960).
3. 3. Phys. Rev. B 4, 155-162 (1971).
4. 3 by hyper-Raman scattering. Phys. Rev. B 26, 5904-5910 (1982).
5. R. Comes, M. Lambert, and A. Guinier, Désordre linéaire dans les cristaux (cas du silicium, du quartz, et des pérovskites ferroélectriques). Acta Crystall. A 26, 254-259 (1970).
6. 3. Sol. Stat. Commun. 61, 21-25 (1987).
7. K. A. Mueller and H. Thomas, Structural Phase Transitions. Berlin, Hong Kong: Springer-Verlag, 1981.
8. B. Zalar, V. V. Laguta, and R. Blinc, NMR evidence for the coexistence of order-disorder and displacive components in barium titanate. Phys. Rev. Lett. 90, 37601-37604 (2003).
9. 3. Sol. Stat. Commun. 117, 483-488 (2001).
10. 3. Sol. Stat. Commun. 91, 465-469 (1994).
11. 3. J. Phys. Condens. Matter 11, 871-879 (1999).
12. K. A. Mueller, Structural Phase Transitions II. Berlin: Springer-Verlag, 1991.
13. 3 - Effect of material processing on Fermi-level position. Phys. Rev. B 48, 7057-7069 (1993).
14. C. J. Lu, S. B. Ren, H. M. Shen, J. S. Liu, and Y. N. Wang, The effect of grain size on domain structure in unsupported PbTiO3 thin films. J. Phys.-Condens. Matter 8, 8011-8016 (1996).
15. 3 powders. J. Am. Cer. Soc. 79, 1053-1060 (1996).
16. 3. Sol. Stat. Commun. 91, 883-887 (1994).
17. W. L. Zhong, Y. X. Wang, C. L. Wang, B. Jiang, and L. A. Bursill, Domain structure in ferroelectric particles. Ferroelectrics 252, 223-231 (2001).
18. 3 films. J. Appl. Phys. 94, 6774-6778 (2003).
19. H. J. Glaesel, E. Hartmann, D. Hirsch, R. Boettcher, C. Klimm, D. Michel, H. C. Semmelhack, J. Hormes, and H. Rumpf, Preparation of barium titanate ultrafine powders from a monomeric metallo-organic precursor by combined solid-state polymerisation and pyrolysis. J. Mater. Sci. 34, 2319-2323 (1999).
20. 3 ceramics. Chem. Phys. Lett. 129, 546-549 (1986).
21. T. Takeuchi, K. Ado, T. Asai, H. Kageyama, Y. Saito, C. Masquelier, and O. Nakamura, Thickness of cubic surface phase on barium titanate single crystalline grains. J. Am. Cer. Soc. 77, 1665-1668 (1994).
22. 3. Helv. Phys. Acta 27, 99-124 (1954).
23. M. H. Frey and D. A. Payne, Grain-size effect on structure and phase transformations for barium titanate. Phys. Rev. B 54, 3158-3168 (1996).
24. M. Tanaka and Y. Makino, Finite size effects in submicron barium titanate particles Ferroelectrics Lett. Sect. 24, 13-23 (1998).
25. M. D. Glinchuk and P. I. Bykov, The peculiarities of the specific heat and dielectric permittivity related to the grain size distribution in ferroelectric nanomaterials. J. Phys. Condens Matter 16, 6779-6788 (2004).