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At high concentrations of the salt, the countercation can even be in the first solvation shell of the anion, i.e., a contact ion pair, or the HOD could form a bridge between the two ions, i.e., a solvent-separated ion pair. In either of these cases or related variants of them, the escape process for the HOD would obviously be altered from that simulated in the present work.
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Actually the authors of ref. 6 adopt a sum of such Gaussian random process descriptions for the bulk OH vibrations and those in the ion solvation shell. We do not adopt this route since there are, for example, issues of the differing intensities of these OH absorptions.
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1 depends on the concentration (see: ref 6a), and 2.2 ps is an extrapolated value for the ∼1 M solution.
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