On the molar volumes and viscosities of electrolytes

Journal of Solution Chemistry

Volumn 35, Issue 9, 2006, Pages 1271-1286

  Marcus, Yizhak ^a  

^a HEBREW UNIVERSITY OF JERUSALEM   (Israel)

Author keywords

Apparent molar volume; Aqueous electrolytes; Non aqueous solutions; Viscosity B coefficient

Indexed keywords

EID: 33750316445     PISSN: 00959782     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10953-006-9058-5     Document Type: Article

References (55)

1. Redlich, O.: Molal volumes of solutes. IV. J. Phys. Chem. 44, 619-629 (1940);
2. Redlich, O., Rosenfeld, P.: The theory of the molal volume of a dissolved electrolyte. II. Z. Elektrochem. 37, 705-711 (1931).
3. Millero, F.J.: The molal volumes of electrolytes. Chem. Rev. 71, 147-176 (1971).
4. Marcus, Y., Hefter, G.: On the pressure and electric field dependencies of the relative permittivity of liquids. J. Solution Chem. 28, 575-592 (1999).
5. Conway, B.E., Verrall, R.E., Desnoyers, J.E.: Partial molal volumes of tetraalkyl-ammonium halides and assignment of individual ionic contributions. Trans. Faraday Soc. 62, 2738-2749 (1966).
6. Desnoyers, J.E., Arel, M., Perron, G., Jolicoeur, C.: Apparent molal volumes of alkali halides in water at 25°. Influence of structural hydration on the concentration dependence. J. Phys. Chem. 73, 3346-3351 (1969).
7. Jenkins, H.D.B., Marcus, Y.: Viscosity B-coefficiets of ions in solution. Chem. Rev. 95, 2695-2724 (1995).
8. Marcus, Y., Hefter, G.: Ion pairing, Chem. Rev., in press (2006).
9. Harned, H.S., Owen, B.B.: The Physical Chemistry of Electrolyte Solutions, Reinhold, New York, 3rd ed. (1958).
10. Marcus, Y.: Electrostriction, ion solvation, and solvent release on ion pairing. J. Phys. Chem. B 109, 18541-18549 (2005).
11. Novotny, P., Söhnel, O.: Densities of binary aqueous solutions of 306 inorganic substances. J. Chem. Eng. Data 33, 49-55 (1988).
12. Marcus, Y.: The thermodynamics of solvation of ions. Part 5 The Gibbs free energy of hydration of ions at 298.15 K. J. Chem. Soc., Faraday Trans. 1, 87, 2995-2997 (1991).
13. Spedding, F.H., Saeger, V.W., Gray, K.A., Boneau, P.K., Brown, M.A., DeKock, C.W., Baker, J.L., Shiers, L.E., Weber, H.O., Habenschuss, A.: Densities and apparent molal volumes of some aqueous rare earth solutions at 25°C. I. Rare earth chlorides. J. Chem. Eng. Data 20, 72-77 (1975);
14. Spedding, F.H., Shiers, L.E., Brown, M.A., Baker, J.L., Gutierrez, L., McDowell, L.S, Habenschuss, A.: Densities and apparent molal volumes of some aqueous rare earth solutions at 25°C. III. Rare earth nitrates. J. Phys. Chem. 79, 1087-1092(1975);
15. Spedding, F.H., Shiers, L.E., Brown, M.A., Derer, J.L. Swanson, D.L, Habenschuss, A.: Densities and apparent molal volumes of some aqueous rare earth solutions at 25°C. II. Rare earth perchlorates. J. Chem. Eng. Data 20, 81-86 (1975).
16. 2 within the temperature range 291.15 to 297.15 K. J. Chem. Eng. Data 41, 397-401 (1996);
17. 2 within the temperature range 291.15 to 297.15 K. J. Chem. Eng. Data 42, 647-650 (1997);
18. 2 from 288.15 to 313.15 K. J. Chem. Eng. Data 44, 1199-1203 (1999);
19. 2 within the temperature range 291.15 to 297.15 K. J. Chem. Eng. Data 45, 1064-1068 (2000).
20. 2 from 15 to 55°C. J. Chem. Eng. Data 33, 370-376 (1988);
21. 2 from 15 to 55°C. J. Chem. Eng. Data 34, 227-232 (1989);
22. Pogue, R.F., Atkinson, G.: Solution thermodynamics of first-row transition elements. 2. Apparent molal volumes of aqueous zinc chloride and zinc perchlorate from 15 to 55°C and an examination of solute-solute and solute-solvent interactions. J. Solution Chem. 18, 249-264 (1989);
23. 2 solutions from 15 to 140°C and from 1 to 200 bar. J. Chem. Eng. Data 36, 449-452 (1991).
24. 2 at 298.15 K. J. Chem. Eng. Data 42, 526-530 (1997).
25. Pilar Pẽna, M., Vercher, E., Martinez-Andreu, A.: Apparent molar volumes of strontium chloride in ethanol + water at 298.15 K. J. Chem. Eng. Data 42, 187-189 (1997).
26. Pasztor, A.J., Criss, C.M.: Apparent molal volumes and heat capacities of some 1:1 electrolytes in anhydrous methanol at 25°C. J. Solution Chem. 7, 27-44 (1978).
27. Vosburgh, W.C., Connell, L.C., Butler, J.A.V.: The electrostriction produced by salts in some aliphatic alcohols. J. Chem. Soc. 1933, 933-942.
28. Kawaizumi, F., Zana, R.: Partial molal volumes of ions in organic solvents from ultrasonic vibration potential and density measurements. 1. methanol. J. Phys. Chem. 78, 627-631 (1974).
29. Mcinnes, D.A., Dayhoff, M.O.: The apparent and partial molal volumes of potassium iodide and of iodine in methanol at 25° from density measurements. J. Am. Chem. Soc. 75, 5219-5220 (1953).
30. Kiepe, J., de Araujo Rodrigues, A. K., Horstmann, S., Gmehling, J.: Experimental determination and correlation of liquid density data of electrolyte mixtures containing water or methanol. Ind. Eng. Chem. Res. 42, 2022-2029 (2003).
31. Skabichevskii, P. A.: Apparent molar volumes of lithium salts in methyl and isoamyl alcohols. Zh. Fiz. Khim. 46, 531-532 (1972);
32. Russ. J. Phys. Chem. 46, 309-310 (1972).
33. Padova, J., Abrahamer, I.: Ion-solvent interactions. VII. Apparent and partial molal volumes of some symmetrical tetraalkylammonium halides in anhydrous methanol solutions. J. Phys. Chem. 71, 2112-2116 (1967).
34. Bottomley, G.A., Bremers, M.T.: Electrolyte molar volumes at 273-373 K in propylene carbonate, N-methylformamide, formamide, and methanol: their relation to solvent compressibility. Ion association constant in acetonitrile at 298 K. Aust. J. Chem. 39, 1959-1981 (1986).
35. Gopal, R., Srivastava, R.K.: Studies on solutions of high dielectric constant, Part II. Partial molal volume of some uni-univalent electrolytes in formamide. J. Indian Chem. Soc. 40, 99-104 (1963).
36. Chen, T., Hefter, G., Buchner, R., Senanayake, G.: Molar volumes and heat capacities of electrolytes and ions in nonaqueous solvents: 1. Formamide. J. Solution Chem. 27, 1067-1096 (1998).
37. Dunn, L.A.: Apparent molar volumes of electrolytes. Part 4, KCl in formamide at 25°C. Trans. Faraday Soc. 67, 2525-2527 (1971).
38. Seidel, W., Luhofer, G.: Apparent molar volumes of some 1,1-electrolytes in N,N-dimethylformamide, propylene carbonate and water. Z. Phys. Chem. (NF) 148, 221-230 (1986).
39. Zana, R., Desnoyers, J.E., Perron, G., Kay, R.L., Lee, K.: Ionic volumes of electrolytes in propylene carbonate from densities, ultrasonic vibration potentials, and transference numbers at 25°C. J. Phys. Chem. 86, 3996-4003 (1982).
40. Muhuri, P.K, Hazra, D.K.: Viscosity B coefficients of some tetraalkylammonium bromides, lithium tetrafluoroborate and tetrabutylammonium tetraphenyl borate in propylene carbonate. Z. Naturforsch., 48a, 523-528 (1993).
41. Chauhan, M.S., Sharma, O.P., Kumar, A., Sharma, K.C., Chauhan, S.: Viscosity study of ion solvation in DMSO-DMF and DMSO-MeOH solvent systems at 25°C. J. Electrochem. Soc. India 47, 187-191 (1998).
42. Zana, R., Perron, G., Desnoyers, J.E.: Ultrasonc vibration potentials apparent molal volumes, and apparent molal heat capacities of 1:1 electrolytes in acetonitrile. J. Solution Chem. 8, 729-753 (1979).
43. Wang, J., Zhao, Y., Zhuo, K., Lin, R.: A partial-molar volume study of electrolytes in propylene carbonate-based lithium battery electrolyte solutions at 298.15 K. Can. J. Chem. 80, 753-760 (2002).
44. Choi, Y.-S., Criss, C.M: Partial molal heat capacities and volumes of electrolytes in nonaqueous solvents and ion-solvent interactions. Disc. Faraday Soc. 64, 204-218 (1978).
45. Lankford, J.I., Criss, C.M.: Partial molar isentropic compressibilities and volumes of selected electrolytes and nonelectrolytes in dimethylsulfoxide. J. Solution Chem. 9, 753-765 (1987).
46. Bicknell, R.T.M., Lawrence, K.G., Feakins, D.: Ionic viscosity B coefficients in dimethyl sulfphoxide at 25, 35 and 45°C. J. Chem. Soc., Faraday Trans. 1 76, 637-647 (1980).
47. Palaiologou, M.M., Molinou, I.E., Tsierkezos, N.G.: Viscosity studies on lithium bromide in water + dimethyl sulfoxide mixtures at 278.15 K and 293.15 K. J. Chem. Eng. Data 47, 1285-1289 (2002).
48. Bobicz, D., Grzybkowski, W.: Apparent molar volumes of multicharged cations in dimethylsulfoxide solutions at 25°C. J. Solution Chem. 31, 223-234 (2002).
49. Krakowiak, K., Bobicz, D., Grzybkowski, W.: Limiting partial molar volumes of tetra-n-alkylammonium perchlorates in N,N-dimethylacetamide, triethylphosphate and dimethyl sulfoxide at T = 298.15 K. J. Chem. Thermodyn. 33, 121-133 (2001).
50. Lawrence, K.G., Sacco, A.: Separation of viscosity B coefficients into ionic contributions. Part 1. Tetrabutylammonium tetrabutylborate and tetraphenyl-phosphonium tetraphenylborate in dimethylsulfoxide. J. Chem. Soc. Faraday Trans. 1 79, 615-624 (1983).
51. Marcus, Y., Hefter, G.: Standard partial molar volumes of electrolytes and ions in nonaqueous solvents. Chem. Rev. 104, 3405-3452 (2004).
52. Marcus, Y., Jenkins, H.D.B., Glasser, L.: Ion volumes - a comparison. J. Chem. Soc., Dalton Trans. 2002, 3795-3798.
53. Marcus, Y.: The solvation number of ions obtained from their entropies of solvation. J. Solution Chem. 15, 291-306 (1986).
54. Patial, B.S., Chauhan, S., Chauhan, M.S., Syal, V.K.: A study of activation parameters for viscous flow process of some tetraalkylammonium salts in binary mixtures of N,N-dimethylformamide and ethyl methyl ketone. Indian J. Chem. A 41, 2039-2045 (2002).
55. Jauhar, S.P., Sandhu, S.: Conductance and viscosity measurements of some 1:1 electrolytes in dimethylformamide + methanol mixtures at 25, 30 and 40°C. Indian J. Chem. A 39, 392 (2000).