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Volumn 6, Issue 10, 2006, Pages 2376-2383

Isomerism in [MCl2ERR′2] (M = Pd, Pt; E = S, Se; R, R′ = Me, Ph)

Author keywords

[No Author keywords available]

Indexed keywords


EID: 33750284897     PISSN: 15287483     EISSN: None     Source Type: Journal    
DOI: 10.1021/cg060348r     Document Type: Article
Times cited : (18)

References (82)
  • 51
    • 33750360622 scopus 로고    scopus 로고
    • note
    • 3m
  • 58
    • 33750349598 scopus 로고    scopus 로고
    • note
    • Before the refinement of the powder pattern, the excess constant background intensity (typically 300-400 counts) was subtracted to diminish the well-known phenomenon of artificial improving of the reliability factors by high background level.
  • 63
    • 33750287394 scopus 로고    scopus 로고
    • note
    • It must be noted that the difficulties in solving the structure of the residual phase 3c originate from the fact that only ∼20% of the intensity gain was caused by this second phase; most of the diffraction peaks were merged partially or completely with the known phase and the weakest diffraction peaks at higher 2θ were missing completely, as they were embedded to the predominant trans-phase 3t.
  • 64
    • 33750308311 scopus 로고    scopus 로고
    • note
    • j is the Brindley particle absorption contrast factor for phase j for which the value of 1 was consistently used to all phases.
  • 70
    • 0003718311 scopus 로고
    • Huzinaga, S., Ed. Physical Science Data 16, Elsevier: Amsterdam
    • Huzinaga, S., Ed. Gaussian Basis Sets for Molecular Calculations; Physical Science Data 16, Elsevier: Amsterdam, 1984.
    • (1984) Gaussian Basis Sets for Molecular Calculations
  • 74
    • 33750372976 scopus 로고    scopus 로고
    • note
    • 31 have demonstrated that in metal complexes containing selenium or tellurium donor atoms this ratio spans a range 1.66-2.11.
  • 79
    • 33750297965 scopus 로고    scopus 로고
    • note
    • 31
  • 80
    • 33750294304 scopus 로고    scopus 로고
    • note
    • 195Pt resonance is consistent with this inference. It is also likely that the two possible diastereoisomers of 5t are also in fast dynamical equilibrium.
  • 82
    • 33750298812 scopus 로고    scopus 로고
    • note
    • The X-ray powder diffraction data of 1t did not indicate disordered chlorine atoms.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.