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Before the refinement of the powder pattern, the excess constant background intensity (typically 300-400 counts) was subtracted to diminish the well-known phenomenon of artificial improving of the reliability factors by high background level.
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It must be noted that the difficulties in solving the structure of the residual phase 3c originate from the fact that only ∼20% of the intensity gain was caused by this second phase; most of the diffraction peaks were merged partially or completely with the known phase and the weakest diffraction peaks at higher 2θ were missing completely, as they were embedded to the predominant trans-phase 3t.
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31 have demonstrated that in metal complexes containing selenium or tellurium donor atoms this ratio spans a range 1.66-2.11.
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33750297965
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note
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31
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80
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33750294304
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note
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195Pt resonance is consistent with this inference. It is also likely that the two possible diastereoisomers of 5t are also in fast dynamical equilibrium.
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82
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note
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The X-ray powder diffraction data of 1t did not indicate disordered chlorine atoms.
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