New sample preparation techniques for the determination of Si isotopic compositions using MC-ICPMS

Chemical Geology

Volumn 235, Issue 1-2, 2006, Pages 95-104

  Georg, R B ^a   Reynolds, B C ^a   Frank, M ^b   Halliday, A N ^c  

^a ETH ZURICH   (Switzerland)

^b GEOMAR HELMHOLTZ CENTRE FOR OCEAN RESEARCH KIEL   (Germany)

^c UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

Ion exchange chromatography; MC ICPMS; Si isotopes

Indexed keywords

CATION; DISSOLUTION; HYDROGEOCHEMISTRY; ISOTOPIC COMPOSITION; MASS SPECTROMETRY; RIVER WATER; SEPARATION; SILICON;

EID: 33750165127     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2006.06.006     Document Type: Article

References (31)

1. Allenby R.J. Determination of the isotopic ratios of silicon in rocks. Geochim. Cosmochim. Acta 5 1 (1954) 40-48
2. Brzezinski M.A., Jones J.L., Bidle K.D., and Azam F. The balance between silica production and silica dissolution in the sea: insights from Monterey Bay, California, applied to the global data set. Limnol. Oceanogr. 48 5 (2003) 1846-1854
3. Cardinal D., Alleman L.Y., de Jong J., Ziegler K., and Andre L. Isotopic composition of silicon measured by multicollector plasma source mass spectrometry in dry plasma mode. J. Anal. At. Spectrom. 18 3 (2003) 213-218
4. Cardinal D., Alleman L.Y., Dehairs F., Savoye N., Trull T.W., and André L. Relevance of silicon isotopes to Si-nutrient utilization and Si-source assessment in Antarctic waters. Glob. Biogeochem. Cycles 17 GB2007 (2005) 10.1029/2004GB002364
5. Clechenko C.C., and Valley J.W. Oscillatory zoning in garnet from the Willsboro Wollastonite Skarn, Adirondack Mts, New York: a record of shallow hydrothermal processes preserved in a granulite facies terrane. J. Metamorph. Geol. 21 8 (2003) 771-784
6. De La Rocha C.L. Measurement of silicon stable isotope natural abundances via multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS). Geochem. Geophys. Geosyst. 3 8 (2002) art. no.-1045
7. De La Rocha C.L., Brzezinski M.A., and DeNiro M.J. Purification, recovery, and laser-driven fluorination of silicon from dissolved and particulate silica for the measurement of natural stable isotope abundances. Anal. Chem. 68 21 (1996) 3746-3750
8. De La Rocha C.L., Brzezinski M.A., and DeNiro M.J. Fractionation of silicon isotopes by marine diatoms during biogenic silica formation. Geochim. Cosmochim. Acta 61 23 (1997) 5051-5056
9. De La Rocha C.L., Brzezinski M.A., DeNiro M.J., and Shemesh A. Silicon-isotope composition of diatoms as an indicator of past oceanic change. Nature 395 6703 (1998) 680-683
10. De La Rocha C.L., Brzezinski M.A., and DeNiro M.J. A first look at the distribution of the stable isotopes of silicon in natural waters. Geochim. Cosmochim. Acta 64 14 (2000) 2467-2477
11. Ding T. Analytical methods for silicon isotope determinations. In: de Groot P.A. (Ed). Handbook of Stable Isotope Analytical Techniques (2004), Elsevier Chapter 25
12. Ding T., Wan D., Wang C., and Zhang F. Large and systematic silicon isotope fractionation discovered in single sticks of bamboo. Goldschmidt Conference 2003. Geochimica et Cosmochimica Acta, Kurashiki, Japan (2003) A79
13. Ding T., Wan D., Wang C., and Zhang F. Silicon isotope compositions of dissolved silicon and suspended matter in the Yangtze River, China. Geochim. Cosmochim. Acta 68 2 (2004) 205-216
14. Ding T., Ma G.R., Shui M.X., Wan D.F., and Li R.H. Silicon isotope study on rice plants from the Zhejiang Province, China. Chem. Geol. 218 1-2 (2005) 41-50
15. Douthitt C.B. The geochemistry of the stable isotopes of silicon. Geochim. Cosmochim. Acta 46 (1982) 1449-1458
16. Engström E., Rodushkin I., Baxter D.C., and Oehlander B. Chromatographic purification for the determination of dissolved silicon isotopic compositions in natural waters by high-resolution multicollector inductively coupled plasma mass spectrometry. Anal. Chem. 78 (2006) 250-257
17. Georg R.B., Reynolds B.C., Halliday A.N., and Zhu C. Fractionation of stable Si isotopes during in-situ dissolution of feldspars and formation of secondary clay minerals. EOS Trans AGU, Fall Meet. Suppl. 86 52 (2005) Abstract
18. Georg, R.B., Reynolds, B.C., Frank, M., Halliday, A.N., in press. Mechanisms controlling the silicon isotopic compositions of river waters. Earth Planet. Sci. Let.
19. Halliday, A.N., Stirling, C.H., Freedman, P.A., Oberli, F., Reynolds, B.C., Georg, R.B., in press. High precision isotope ratio measurements using multiple collector inductively coupled plasma mass spectrometry, Encyclopedia of Mass Spectrometry, Chapter 17.
20. Karl D.M., and Tien G. Magic - a sensitive and precise method for measuring dissolved phosphorus in aquatic environments. Limnol. Oceanogr. 37 1 (1992) 105-116
21. Potts P.J. A Handbook of Silicate Rock Analysis (1987), Blackie Academics & Professional 622 pp.
22. Reynolds J.H., and Verhoogen J. Natural variations in the isotopic constitution of silicon. Geochim. Cosmochim. Acta 3 (1953) 224-234
23. Reynolds J.H., and Verhoogen J. Natural variations in the isotopic constitution of silicon. Geochim. Cosmochim. Acta 3 5 (1953) 224-234
24. Reynolds B.C., Frank M., and Halliday A.N. Silicon isotope fractionation during nutrient utilization in the North Pacific. Earth Planet. Sci. Lett. 244 (2006) 431-443
25. Reynolds B.C., Georg R.B., Oberli F., Wiechert U.H., and Halliday A.N. Re-assessment of silicon isotope reference materials using high-resolution multi-collector ICP-MS. J. Anal. At. Spectrom. 21 3 (2006) 266-269
26. Riley J.P. The rapid analysis of silicate rocks and minerals. Anal. Chim. Acta 19 (1958) 413-428
27. Tilles D. Natural variations in isotopic abundances of silicon. J. Geophys. Res. 66 (1961) 3003-3014
28. Varela D.E., Pride C.J., and Brzezinski M.A. Biological fractionation of silicon isotopes in Southern Ocean surface waters. Glob. Biogeochem. Cycles 18 GB1047 (2004) 1-8
29. Walsh J.N., Buckley F., and Barker J. The simultaneous determination of rare-earth elements in rocks using inductively coupled plasma source spectrometry. Chem. Geol. 33 (1981) 141-153
30. Wickbold R. Die Anreicherung sehr kleiner Mengen Kieselsäure durch Ionenaustausch. Fresenius Z. Anal. Chem. 171 2 (1959) 81-87
31. 28Si of meteorites and Allende inclusions. Lunar Planet. Sci. IX 2 (1978) 1289-1291