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46149094085
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All new compounds have spectroscopic and analytical data consistent with the assigned structure
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All new compounds have spectroscopic and analytical data consistent with the assigned structure.
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26
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0001249486
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31
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46149086267
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Colorless oil. Rf (hexanes/EtOAc 90:10, 0.15, α]D, 27.5 (c 1.22, CHCl3, IR (film, 2975, 1728 cm-1. 1H NMR (500 MHz, CDCl3) δ 4.25 (1H, d, J, 2.4 Hz, CH3COCHO, 4.06 (1H, dd, J, 11.1 Hz, J, 4.5 Hz, CHxHyOOCtBu, 3.85 (1H, dd, J, 11.1 Hz, J, 6.0 Hz, CHx HyOOCtBu, 3.66 (1H, dd, J, 9.9 Hz, J, 2.1 Hz, CH3CH(CH2) CHO, 2.18 (3H, s, CH3CO, 2.06-2.00 (1H, m, CH3CH (CHO)2, 2.00-1.92 (1H, m, CH3CH CH2, 1.49, 3H, s, CH3CCH3, 1.42 (3H, s, CH3CCH3, 1.21 (9H, s, CH3)3COO, 1.01 (3H, d, J, 6.6 Hz, CH3, 0.86 3H, d, J
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+: 315.2171; found: 315.2174.
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