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18 ohms). After sampling, the water sample plus 80 ml of aqua regia and 80 ml of deionized water, which were used to rinse the sampler of any precipitates, were combined into a high-density polyethylene plastic bottle before analysis by inductively coupled plasma mass spectrometry at the Commonwealth Scientific and Industrial Research Organisation (CSIRO) Energy Technology Centre for Advanced Analytical Chemistry in Lucas Heights, Australia. Sample PW24 was collected primarily to determine the major aqueous species, and only a 50-ml aliquot, with 1 ml of aqua regia added, was analyzed for trace metals. The restricted access to wells limited the number of down-hole samples obtained for trace-metal analyses and prevented replicate sampling or field blanks. GW06 was sampled on two consecutive days, first for major aqueous species and then for trace metals, followed by trace-metal sampling of PW24 and then GW14. Between 680 and 780 ml of clear liquid with trace sediment or precipitate was obtained in the sampling runs. The results and the order in which the wells were sampled indicate no cross-contamination and yield reproducible analyses of two distinct deepwater samples. A field blank from a New Zealand geothermal well, obtained with the same sampler under similar down-hole conditions, shows that background levels are well below the concentrations measured in the Ladolam geothermal brine (Table 2).
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33750021612
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A. A. Longo, thesis, Oregon State University (2005)
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A. A. Longo, thesis, Oregon State University (2005).
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33750009494
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note
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We thank Lihir Gold Ltd. for field support, gold assays of deep drill cuttings, geothermal brine data, and permission to publish this manuscript. Research funding was provided by the Foundation for Research Science and Technology. Comments from P. R. L. Browne, J. W. Hedenquist, W. E. Seyfried, and N. C. White improved this manuscript.
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