Mathematical modeling of continuous production of carbon nanofibers from methane in a reactor with a moving bed of a nickel-containing catalyst

Theoretical Foundations of Chemical Engineering

Volumn 40, Issue 5, 2006, Pages 519-525

  Zavarukhin, S G ^a   Kuvshinov, G G ^b  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^b NOVOSIBIRSK STATE TECHNICAL UNIVERSITY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

FLOW RATES; LONGITUDINAL COORDINATE; MATHEMATICAL MODELING; METHANE CONVERSION;

CATALYSTS; COMPUTER SIMULATION; MATHEMATICAL MODELS; METHANE; NICKEL; PARAMETER ESTIMATION;

CARBON NANOTUBES;

EID: 33749983380     PISSN: 00405795     EISSN: None     Source Type: Journal    
DOI: 10.1134/S0040579506050095     Document Type: Article

References (32)

1. Baker, R.T.K. and Harris, P.S., The Formation of Filamentous Carbon, Chem. Phys. Carbon, 1978, vol. 14, p. 83.
2. Rodrigues, N.M., A Review of Catalytically Grown Carbon Nanofibers, J. Mater. Res., 1993, vol. 8, no. 12, p. 3233.
3. Chesnokov, V.V. and Buyanov, R.A., Formation of Carbon Fibers in Catalytic Decomposition of Hydrocarbons on Iron Group Metals and Their Alloys, Usp. Khim., 2000, vol. 69, no. 7, p. 675.
4. Frantsuzov, V.K., Petrusenko, A.P., Peshnev, B.V., and Lapidus, A.L., Filamentous Carbon and Its Technical Application Fields, Khim. Tverd. Topi., 2000, no. 2, p. 52.
5. Jong, K.P. and Geus, J.W., Carbon Nanofibers: Catalytic Synthesis and Applications, Catal. Rev. Sci. Eng., 2000, vol. 42, no. 4, p. 481.
6. Rakov, E.G., Chemistry and Application of Carbon Nanotubes, Usp. Khim., 2001, vol. 70, no. 10, p. 934.
7. Serp, P., Corrias, M., and Kalck, P., Carbon Nanotubes and Nanofibers in Catalysis, Appl. Catal. A: Gen., 2003, vol. 253, p. 337.
8. Fenelonov, V.B., Avdeeva, L.B., Zheivot, V.I., Okkel, L.G., Goncharova, O.V., and Pimneva, L.G., Texture and Absorption Properties of Filamentous Carbon Produced by Decomposition of Carbon-Containing Gases on Metal Catalysts, Kinet. Katal., 1993, vol. 34, no. 3, p. 545.
9. Kuvshinov, G.G., Avdeeva, L.B., Goncharova, O.V., and Mogil'nykh, Yu.I., Peculiarities of the Process of Producing the Granular Carbon Materials of Fibrous Structure by Hydrocarbon Decomposition in Unstatic Catalyst Bed Reactor, ACHEMA'94. International Meeting on Chemical Engineering and Biotechnology. Extended Abstracts of the Lecture Group "Thermal Process Engineering," Frankfurt am Main, Germany, June 5-11, 1994, p. 96.
10. Rodrigues, N.M., Kim, M.S., and Baker, R.T.K., Carbon Nanofibers: A Unique Catalyst Support Medium, J. Phys. Chem., 1994, vol. 98, p. 13108.
11. Kuvshinov, G.G., Mogil'nykh, Yu.I., and Lebedev, M.Yu., Application of Filamentous Carbon as a Catalyst for Direct Oxidation of Hydrogen Sulfide to Sulfur, Khim. Prom-st., 1999, no. 1, p. 26.
12. Kovalenko, G.A., Kuznetsova, E.V., Mogilnykh, Yu.I., Andreeva, I.S., Kuvshinov, D.G., and Rudina, N.A., Catalytic Filamentous Carbons for Immobilization of Biologically Active Substances and Non-Growing Bacterial Cell, Carbon, 2001, vol. 39, p. 1033.
13. Rakov, E.G., Methods for Continuous Production of Carbon Nanofibers and Nanotubes, Khim. Tekhnol., 2003, no. 10, p. 2.
14. Frantsuzov, V.K., Peshnev, B.V., Nikolaev, A.L., et al., Study of Macrokinetic Features of the Formation of Filamentous Carbon in a Pouring-Type Reactor, Khim. Prom-st., 1997, no. 9, p. 611.
15. 3 Catalyst Support for Large-Scale Production, Chem. Phys. Lett., 2003, vol. 378, p. 9.
16. Rakov, E.G., Blinov, S.N., Ivanov, I.G., Rakova, E.V., and Digurov, N.G., Continuous Process for Obtaining Carbon Nanofibers, Zh. Prikl. Khim., 2004, vol. 77, no. 2, pp. 193-197
17. [Russ. J. Appl. Chem. (Engl. Transl.), vol. 77, no. 2, pp. 187-191].
18. Zavarukhin, S.G., Mogil'nykh, Yu.I., and Kuvshinov, G.G., Modeling of Production of Catalytic Filamentous Carbon in an Isothermal Well-Stirred Reactor, Khim. Prom-st., 1999, no. 10, p. 641.
19. Kuvshinov, G.G., Zavarukhin, S.G., and Zhdanova, E.S., Modeling of Production of Catalytic Filamentous Carbon from a Methane-Hydrogen Mixture in a Batch Fluidized-Bed Reactor, Nauchn. Vestn. Novosibirsk. Cos. Tekh. Univ., 1999, no. 2(7), p. 127.
20. Grujicic, M., Gao, G., and Gersten, B., Optimization of the Chemical Vapor Deposition Process for Carbon Nanotubes Fabrication, Appl. Surf. Sci., 2002, vol. 199, p. 90.
21. Zavarukhin, S. and Kuvshinov, G., Catalytic Synthesis of Nanofibrous Carbon from Methane in Isothermal Reactors of Different Types, Proc. Carbon'03: An International Conference on Carbon, Oviedo, Spain, July 6-10, 2003, p. 175.
22. 2 Mixture over a High-Loaded Nickel Catalyst with Consideration for the Catalyst Deactivation, Appl. Catal. A, 2004, vol. 272, p. 219.
23. Goncharova, O.V., Avdeeva, L.B., Fenelonov, V.B., Plyasova, L.M., Malakhov, V.V., Litvak, G.S., and Vlasov, A.A., High-Loaded Ni-Al Catalysts for Methane Decomposition: I. Formation of the Active Component Phase Structure, Kinet. Katal., 1995, vol. 36, no. 2, p. 293.
24. Avdeeva, L.B., Goncharova, O.V., Kochubey, D.I., Zaikovskii, V.I., Plyasova, L.M., Novgorodov, B.N., and Shaikhutdinov, Sh.K., Coprecipitated Ni-Alumina and Ni-Cu-Alumina Catalysts of Methane Decomposition and Carbon Deposition: II. Evolution of the Catalysts in Reaction, Appl. Catal. A: Gen., 1996, vol. 141, p. 117.
25. Ermakova, M.A., Ermakov, D.Yu., Kuvshinov, G.G., and Plyasova, L.M., New Nickel Catalysts for the Formation of Filamentous Carbon in the Reaction of Methane Decomposition, J. Catal., 1999, vol. 187, p. 77.
26. Ermakova, M.A., Ermakov, D.Yu., and Kuvshinov, G.G., Effective Catalysts for Direct Cracking of Methane to Produce Hydrogen and Filamentous Carbon: Part I. Nickel Catalysts, Appl. Catal. A: Gen., 2000, vol. 201, p. 61.
27. Kuvshinov, G.G., Mogilnykh, Yu.I., Kuvshinov, D.G., Yermakov, D.Yu., Yermakova, M.A., Salanov, A.N., and Rudina, N.A., Mechanism of Porous Filamentous Carbon Granule Formation on Catalytic Hydrocarbon Decomposition, Carbon, 1999, vol. 37, p. 1239.
28. Kuvshinov, G.G., Mogilnykh, Yu.I., Kuvshinov, D.G., Zaikovskii, V.I., and Avdeeva, L.B., Peculiarities of Filamentous Carbon Formation in Methane Decomposition on Ni-Containing Catalysts, Carbon, 1998, vol. 36, p. 87.
29. Kuvshinov, G.G., Environmentally Sound Nontraditional Processings of Hydrocarbon Energy Carrier to Produce and Use Hydrogen, Proc. Third Int. Conf. on New Energy Systems and Conversions, Kazan, Russia, September 8-13, 1997, p. 47.
30. Kuvshinov, G.G., Zavarukhin, S.G., Mogil'nykh, Yu.I., et al., Implementation of Production of Granular Catalytic Filamentous Carbon on the Scale of a Pilot Reactor, Khim. Prom-st., 1998, no. 5, p. 300.
31. Kuvshinov, G.G., Mogil'nykh, Yu.I., Kuvshinov, D.G., et al., Kinetic Features of the Formation of Filamentous Carbon in Methane Decomposition on Nickel-Containing Catalysts, Khim. Prom-st., 1997, no. 4, p. 270.
32. 2 Mixtures over a Nickel Containing Catalyst, Catal. Today, 1998, vol. 42, p. 357.