Shear viscosities of methycyclohexane, perfluoromethylcyclohexane, and their mixtures in the vicinity of the upper critical mixing temperature. 1. Critical isopleth and coexistence curve

Journal of Chemical and Engineering Data

Volumn 51, Issue 5, 2006, Pages 1502-1508

  Davies, Michael K ^a   Archer, Amanda L ^a   Maczek, Andrew O S ^a   Manzanares Papayanopoulos, Emilio ^b   McLure, Ian A ^a  

^a UNIVERSITY OF SHEFFIELD   (United Kingdom)

^b INSTITUTO DE INVESTIGACIONES ELÉCTRICAS   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

CAPILLARY RHEOMETER; CRITICAL SOLUTION TEMPERATURE; METHYCYCLOHEXANE; PERFLUOROMETHYLCYCLOHEXANE (PFMCH); SHEAR VISCOSITY;

FLUORESCENCE; POLARIZATION; RHEOLOGY; RHEOMETERS; SHEAR STRENGTH; THERMOANALYSIS; VISCOSITY;

ORGANIC COMPOUNDS;

EID: 33749843629     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je0502593     Document Type: Article

References (49)

1. Sengers, J. V. Transport properties of fluids near critical points. Int. J. Thermophys. 1985, 6, 203-232.
2. Nieuwoudt, J. C.; Sengers, J. V. A reevaluation of the viscosity exponent for binary mixtures near the consolute point. J. Chem. Phys. 1989, 90, 457-462.
3. Zielesny, A.; Woermann, D. Crossover behaviour and critical amplitude of the viscosity of binary liquid mixtures of critical composition. J. Chem. Soc., Faraday Trans. 1994, 90 (15), 2215-2222.
4. Zielesny, A.; Schmitz, J.; Limberg, S.; Aizpiri, A. G.; Fusenig, S.; Woermann, D. Viscosity and diffusivity of a binary liquid mixture of critical composition - study of the system 2-butoxyethanol/water. Int. J. Thermophys. 1994, 15, 67-94.
5. Das, P.; Bhattacharjee, J. Zero-frequency critical bulk viscosity: is the amplitude ratio truly universal? Phys. Rev. E 2001, 64, 022201-022204.
6. Berg, R. F.; Moldover, M. R. Critical exponent for the viscosity of four binary liquids. J. Chem. Phys. 1988, 89, 3694-3704.
7. Berg, R. F. Critical exponent for viscosity. Phys. Rev. A 1990, 42, 7183-7186.
8. Berg, R. F.; Moldover, M. R. Critical exponent for the viscosity of carbon dioxide and xenon. J. Chem. Phys. 1990, 93, 1926-1938.
9. Berg, R. F.; Moldover, M. R.; Zimmerli, G. A. Frequency-dependent viscosity of xenon near the critical point. Phys. Rev. E1999, 60, 4079-4098.
10. Hao, H.; Ferrell, R. A.; Bhattacharjee, J. K. Critical viscosity exponent for classical fluids. Phys. Rev. E 2005, 71, 021201-021213.
11. Dyke, D. E. L.; Rowlinson, J. S.; Thacker, R. The physical properties of some fluorine compounds and their solutions. Part 4. Solutions in hydrocarbons. Trans. Faraday Soc. 1959, 55, 903-910.
12. Sundquist, B. E.; Oriani, R. A. Thermodynamics of a miscibility gap system and a test of nucleation theory. Trans. Faraday Soc. 1967, 63, 561-568.
13. Sundquist, B. E.; Oriani, R. A. Homogeneous nucleation in a miscibility gap system. A critical test of nucleation theory. J. Chem. Phys. 1967, 39, 2604-2615.
14. Hurle, R. L.; Young, C. L.; Toczylkin, L. S. Theoretical predictions of phase equilibria at high temperatures and pressures for nonpolar mixtures. Part 3. Comparison of the upper critical solution temperatures for perfluoromethylcyclohexane + hydrocarbons. J. Chem. Soc., Faraday Trans. 2 1977, 73, 618-622.
15. Kumaran, M. K.; McGlashan, M. L. Critical exponents for (methyl-cyclohexane + perfluoromethylcyclohexane) from measurements of excess volumes close to the critical mixing temperature. Aust. J. Chem. 1990, 33, 1909-1919.
16. Kumaran, M. K. Molar volume of (methylcyclohexane + perfluoromethylcyclohexane) in the critical region. J. Chem. Thermodyn. 1981, 13 (8), 789-794.
17. McLure, I. A.; Williamson, A.-M.; Fernández, J. Orthobaric surface tension of (methylcyclohexane + tetradecafluoromethylcyclohexane) in the critical region from 320 to 335 K. J. Chem. Thermodyn. 1994, 26, 897-911.
18. Xu, S.; Ballard, L.; Kim, Y. J.; Jonas, J. Dynamic structure of methylcyclohexane and perfluoromet̀hylcyclohexane liquids in confinement and in bulk. J. Phys. Chem. 1995, 99, 5787-5792.
19. McLure, I. A.; Williamson, A.-M. Wetting near consolute points by evanescent-wave-generated fluorescence spectroscopy. 1. Differential solubility: 2,6-lutidine + water at the lower critical endpoint. Physica A 1996, 234 (1-2), 206-224.
20. Neilson, M. M.; Bowers, J.; Manzanares-Papayanopoulos, E.; Howse, J. R.; Vergara-Gutierrez, M. C.; Clements, P. J.; Burgess, A. N.; McLure, I., A. Neutron reflectivity studies of the free liquid surface of methylcyclohexane + tetradecafluoromethylcyclohexane near the critical endpoint. Phys. Chem. Chem. Phys. 1999, 1, 4635-4643.
21. Kumaran, M. K.; Benson, G. C. Effect of pressure on the critical solution temperature of (methylcyclohexane + perfluoromethylcyclohexane). Fluid Phase Equilib. 1983, 11, 13-18.
22. Maczek, A. O. S.; Davies, M. K.; Jayasuriya, J. E. C. Amplitude ratios for viscosity and thermal-conductivity anomalies near a UCST. Der. Bunsen-Ges. Phys. Chem. 1990, 94, 425-428.
23. Maczek, A. O. S.; Davies, M. K. Anomalous thermal conductivity in the close neighbourhood of a UCST. Her. Bunsen-Ges. Phys. Chem. 1990, 94, 420-424.
24. McLure, I. A.; Manzanares-Papayanopoulos, E. Representation of the near-critical shear viscosity of mixtures along the liquid-liquid coexistence curve (Manuscript in preparation).
25. Pegg, I. L.; McLure, I. A. Shear viscosity through the consolute point for three binary liquid mixtures. Mol. Phys. 1984, 53, 897-916.
26. Chu, B.; Lin, F. L. Laser light scattering study of a ternary liquid mixture. Ethanol-water-chloroform. J. Chem. Phys. 1974, 61, 5132-5146.
27. Bogue, D. C. Entrance effects and prediction of turbulence in non-Newtonian flow. Ind. Eng. Chem. 1959, 51, 874-878.
28. Davies, M. K. Transport properties near the upper critical solution temperature of a binary liquid mixture. Ph.D. Thesis, University of Sheffield, 1988.
29. Cannon, M. R.; Manning, R. E.; Bell, J. D. Viscosity measurements: the kinetic energy correction and a new viscometer. Anal. Chem. 1960, 32, 355-358.
30. Kell, G. S. Density, thermal expansivity, and compressibility of liquid water from 0° to 150°C: correlations and tables for atmospheric pressure and saturation reviewed and expressed on 1968 temperature scale. J. Chem. Eng. Data 1975, 20, 97-105.
31. Künzel, W.; Van Wijk, H. F.; Marsh, K. N. Viscosity. In IUPAC Recommended Reference Materials for the Realization of Physicochemical Properties; Marsh, K. N., Ed.; Blackwell Scientific Publications: Oxford, 1987; Chapter 4.
32. Bevington, P. R. Data Reduction and Error Analysis for the Physical Sciences; McGraw-Hill: New York, 1969.
33. Archer, A. L. Alkane + perfluoroalkane mixtures: a theoretical and experimental study of near-critical phase equilibria, thermodynamics and transport properties. Ph.D. Thesis, University of Sheffield, 1995.
34. McLure, I. A.; Manzanares-Papayanopoulos, E.; Archer, A. L.; Maczek, A. O. S.; Clements, P. J. Shear viscosities of methylcyclohexane, tetradecafluoromethylcyclohexane and their mixtures in the vicinity of the upper critical mixing temperature. II Critical isotherm (Manuscript in preparation).
35. McLure, I. A.; Clements, P. J. Shear viscosity of hexane + tetradecafluorohexane near the upper critical endpoint. Ber. Bunsen-Ges. Phys. Chem. 1997, 101 (1), 114-119.
36. Clements, P. J. Critical point behaviour in binary and ternary liquid mixtures. Ph.D. Thesis, University of Sheffield, 1996.
37. Reed, T. M., III; Taylor, T. E. Viscosities of liquid mixtures. J. Phys. Chem. 1959, 63, 58-67.
38. Debye, P. Polar Molecules; Dover: New York, 1929.
39. Ohta, T. Multiplicative renormalization of the anomalous shear viscosity in classical liquids. J. Phys. C 1977, 10, 791-793.
40. Siggia, E. D.; Halperin, B. I.; Hohenberg, P. C. Renormalization-group treatment of the critical dynamics of the binary-fluid and gas-liquid transitions. Phys. Rev. B 1976, 13, 2110-2123.
41. Calmettes, P. Critical transport properties of fluids. Phys. Rev. Lett. 1977, 59, 1151-1154.
42. Oxtoby, D. W. Nonlinear effects in the shear viscosity of fluids near the critical point. J. Chem. Phys. 1975, 62, 1463-1468.
43. Manzanares-Papayanopoulos, E. Bulk and interfacial molecular structure near liquid-liquid critical points. Ph.D. Thesis, University of Sheffield, 2000.
44. Pegg, I. L. Interfaces in near-critical binary liquid mixtures: a classical and light-scattering study. Ph.D. Thesis, University of Sheffield, 1982.
45. McLure, I. A.; Barbarin-Castillo, J.-M. The orthobaric liquid and vapour densities of tetramethylsilane and of 2,2-dimethylpropane. Int. J. Thermophys. 1993, 14, 1173-1186.
46. Le Guillou, J. S.; Zinn-Justin, J. Critical exponents from field theory. Phys. Rev. 1980, B21, 3976-3998.
47. Wegner, F. J. Corrections to scaling laws. Phys. Rev. B 1972, 5, 4529-4536.
48. Calmettes, P. Universal ratios of critical amplitudes for the shear viscosity. J. Phys. Lett. 1979, 40, 535-538.
49. Drozd-Rzoska, A. Shear viscosity studies above and below the critical consolute point in a nitrobenzene-decane mixture. Phys. Rev. E 2000, 62, 8071-8075.