Adsorption of CO molecules on Rh low index and (331) stepped surfaces

Chinese Science Bulletin

Volumn 49, Issue 10, 2004, Pages 1012-1019

  Wang, Zexin ^a   Pang, Xuehui ^a   Rui, Wang ^a  

^a SHANDONG NORMAL UNIVERSITY   (China)

Author keywords

(331) stepped surface; 5 MP; CO Rh system; Dactylogram; Eigenvibration; Extended LEPS potential; Surface adsorption; Terrace

Indexed keywords

EID: 33749819042     PISSN: 10016538     EISSN: 18619541     Source Type: Journal    
DOI: 10.1360/03wb0127     Document Type: Article

References (40)

1. Hove, M. A. V., Koestner, R. J., Frost, J. C. et al., The structure of Rh(111)(2×2)-3CO from LEED intensities: Simultaneous bridge and near-top adsorption in a distorted compact hexagonal CO overlayer. Surf. Sci., 1983, 129: 482-506.
2. 2 on Rh(111) studied by high resolution electron energy loss spectroscopy, Surf. Sci., 1980, 91: 514-532.
3. Kose, R., Brown, W. A., King, D. A., Role of Lateral Interaction in Adsorption Kinetics: CO/Rh{100}, J. phys. Chem. B, 1999, 103: 8722-8725.
4. Leung, L. W. H., He, J. W., Goodman, D. W., Adsorption of CO on Rh(100) studied by infrared reflection-absorption spectroscopy, J. Chem. Phys., 1990, 93: 8328-8336.
5. Chang, Si-Chung., Weaver, M. J., Coverage- and potential-dependent binding geometries of carbon monoxide at ordered low-index platinum- and rhodium-aqueous interfaces: comparisons with adsorption in corresponding metal-vacuum environments. Surf. Sci., 1990, 238: 142-162.
6. Kizhakevariam, N., Weaver, M. J., Bimetallic electrochemical interfaces: carbon monoxide coadsorbed with copper and lead on ordered low-index rhodium surfaces, Surf. Sci., 1992, 277: 21-30.
7. Batteas, J. D., Barbieri, A., Starkey, E. K. et al., A tensor LEED analysis of the Rh(110)-p2mg(2×1)-2CO structure. Surf. Sci., 1994, 313: 341-348.
8. DeLouise, L. A., White, E. J., Winograd, N., CHaracterization of CO binding sites on Rh{111} and Rh{331} surfaces by XPS and LEED: Comparison to EELS results, Surf. Sci., 1984, 147: 252-262.
9. Smedh, M., Beutler, A., Ramsvik, T. et al., Vibrationally resolved C 1s photoemission from CO absorbed on Rh(111): the investigation of a new chemically shifted C 1s component, Surf. Sci., 2001, 491: 99-114.
10. Linke, R., Curulla, D., Hopstaken, M. J. P. et al., CO/Rh(111): Vibrational frequency shifts and lateral interactions in adsorbate layers, J. Chem. Phys., 2001, 115(17): 8209-8216.
11. Jong, A. M. de., Niemantsverdriet, J. W., The adsorption of CO on Rh(100): Reflection absorption infrared spectroscopy, low energy electron diffraction, and thermal desorption spectroscopy, J. Chem. Phys., 1994, 101: 10126-10133.
12. Thiel, P. A., Williams, E. D., Yates, J. T. et al., The chemisorption of Co on Rh(111), Surf. Sci., 1979, 84: 54-64.
13. Hove, M. A. V., Gierer, M., Barbieri, A. et al., Structural reanalysis of the Rh(111)+(√3 × √3)R30°-CO and Rh(111)+(2×2)-3CO phases using automated tensor LEED, Surf. Sci., 1997, 391: 176-182.
14. Wagner, F. T., Moylan, T. E., Schmieg, S. J., Hydrophilic versus hydrophobic coadsorption: Carbon monoxide and water on Rh(111) versus Pt(111), Surf. Sci., 1988, 195: 403-428.
15. Dubois, L. H., Hansma, P. K., Somorjai, G. A., Evidence for an oxygen intermediate in the catalytic reduction of NO by CO on rhodium surfaces, J. of Catal., 1980, 65: 318-327.
16. Wang, Z. X., Tian, F. H., The Adsorption of O Atom on Cu(100), (110), (111) low index and step defect Surfaces, J. Phys. Chem. B, 2003, 25: 6153-6161.
17. Wang, Z. X., Jia, X. F., Tian, F. H. et al., Oxygen atom adsorption and diffusion on Pd low-index surfaces and (311) stepped surface, Chin. J. of Chem. (in Chinese), 2004, 22: 152-158.
18. Wang, Z. X., Qiao, Q. A., Chen, S. G. et al., The adsorption of O and CO on low index Ni planes and stepped nickel surfaces. Surf. Sci., 2002, 517: 29-42.
19. McCreey, J. H., Wolken, J., A model potential for chemisorption: H2+W(001), J. Chem. Phys., 1975, 63: 2340-2349.
20. McCreey, J. H., Wolken, J., Dynamics of adsorption on covered surfaces, J. Chem. Phys., 1977, 66: 2316-2321.
21. Huber, G. A., Herzberg, G., Mol. Sped. Mol. Struct. Iv. D. Van Nostcand, New York: Reinhild, 1979.
22. Gurney, B. A., Richter, L. J., Villarrubia, J. S. et al., The populations of bridge and top site CO on Rh(100) vs coverage, temperature, and during reaction with O, J. Chem. Phys., 1987, 87: 6710-6721.
23. He, J.-W., Kuhn, W. K., Leung, L.-W. H. et al., Infrared vibrational studies of CO adsorption on ultrathin Cu films on a Rh(100) surface, J. Chem. Phys., 1990, 93: 7463-7470.
24. Chang, Si-Chung., Weaver, M. J., The characterization of carbon monoxide electrosorbed on ordered rhodium (100) by in-situ infrared spectroscopy, J. Elec. Chem., 1990, 285: 263-272.
25. Goursot, A., Papai, I., Salahub, D R., Density functional study of carbon monmoxide chemisorption on model clusters of rhodium and palladium: a comparative analysis of the site selection, J. Amar. Chem. Soc., 1992, 114(19): 7452-7458.
26. Richter, L. J., Gurney, B. A., Ho, W., The influence of adsorbate-adsorbate interactions on surface structure: The coadsorption of CO and H2 on Rh(100), J. Chem. Phys., 1987, 86: 477-490.
27. Ka, C.-T., Blackman, G. S., Hove, M. A. Van, et al., The surface structure and chemical reactivity of Rh(111)-(2×2)-3NO by HREELS and dynamical LEED analysis, Surf. Sci., 1989, 224: 77-96.
28. Hove, M. A. V., Koestner, R. J., Somorjai, G. A. Low-energy electron-diffraction intensity analysis of a surface structure with three CO molecules in the unit cell, Rh(111)-(2×2)-3CO: Compact adsorption in simultaneous bridge and nonsymmetric Near-Top Sites, Phys. Rev. Lett., 1983, 50(12): 903-906.
29. Crowell, J. E., Somorjal, G. A., The effect of potassium on the chemisorption of cabbon monoxide on the Rh(111) crystal face, Appl. Surf. Sci., 1984, 19: 73-91.
30. Zhang, C. J., Hu, P., Lee, M. H., A density functional theory study on the interaction between chemisorbed CO and S on Rh(111), Surf. Sci., 1999, 432: 305-315.
31. Koestner, R. J., Hove, M. A. V., Somorjai, G. A., Surface crystallography study by dynamical LEED of the (√3 × √3) R30° CO structure on the Rh(111) crystal surface. Surf. Sci., 1981, 107: 439-458.
32. α-DV. Acta Phsy. Sinica, 1985, 34(10): 1299-1304.
33. Richter, L. J., Germer, T. A., Ho, W., Coadsorption-induced site changes: Bridging hydrogen from CO and H on Rh(100), Surf. Sci., 1988, 195: L182-L192.
34. Root, T. W., Fisher, G. B., Schmidt, L. D., Electron energy loss characterization of NO on Rh(111), II. Coadsorption with oxygen and CO, J. Chem. Phys., 1986, 85: 4687-4695.
35. Leung, L.-W. H., Chang, S.-C., Weaver, M. J., Electrochemical infrared spectroscopy of carbon monoxide on ordered rhodium (111): Comparisons with vibrational spectra on Pt(111) and in re- lated surface-vacuum environments, J. Chem. Phys., 1989, 90: 7426-7435.
36. Klivenyi, G., Solymosi, F., HREELS study on the effect of iodine on the bonding of CO on Rh(111), Surf. Sci., 1999, 420: 17-24.
37. Cernota, P. L., Reder, K., Yoon, H. A. et al., Dense structures formed by CO on Rh(111) studied by scanning tunneling microscopy. Surf. Sci., 2000, 445: 249-255.
38. Sheppard, N., Nguyen, T. T., Advances in Infrared and Raman Spectroscopy, Vol. 5 (eds. Clark, R. J. H., Hester, R. E.), London: Heyden & Son, 1978, 67.
39. Yang, A. C., Garland, C. W., Susceptibility and curie point of magnetically dilute crystals, J. Chem. Phys., 1957, 26: 1504-1507.
40. 2 and C) chemisorbed on the stepped rhodium (755) and (331) surfaces, Surf. Sci., 1979, 83: 60-82.