Closed-form expressions of quantum electron transfer rate based on the stationary-phase approximation

Journal of Physical Chemistry B

Volumn 110, Issue 38, 2006, Pages 18996-19003

  Jang, Seogjoo ^a   Newton, Marshall D ^b  

^a CITY UNIVERSITY OF NEW YORK   (United States)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; FERMI LEVEL; FREE ENERGY; INTERPOLATION; MATHEMATICAL MODELS; QUANTUM THEORY; SPECTRUM ANALYSIS;

CLOSED-FORM RATE EXPRESSIONS; INTERPOLATION FORMULA; OHMIC SPECTRAL DENSITY; STATIONARY-PHASE APPROXIMATION;

ELECTRON TRANSITIONS;

EID: 33749635795     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp061329v     Document Type: Article

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60. There is a typo in the rate expression provided in ref 31. Refer to eq 13 and the following paragraph of the present paper for the correct expression.
61. BT) ≪ 1 for all the ω with nonnegligible contribution to J(ω).
62. It should be noted that the term "reorganization" is used in a loose sense here, and that these quantum "reorganization" energies do not necessarily have clear physical interpretation.
63. It appears that this form provides a reasonable interpolation of the three stationary-phase approximations according to our numerical tests, but we cannot identify a clear physical basis for choosing this type of interpolation formula.