Electrocatalytic reductive dimerization of the 2,2′-bipyridyl tungsten alkylidyne complex [W({triple bond, long}CC6H4NMe2-4)(NCMe)(CO)2{κ2-2,2′-(NC5H4)2}]+

Journal of Organometallic Chemistry

Volumn 691, Issue 22, 2006, Pages 4660-4666

  Duplessis, Elizabeth A ^a   Jelliss, Paul A ^a   Kirkpatrick, Charles C ^a   Minteer, Shelley D ^a   Wampler, Keith M ^a  

^a Saint Louis University   (United States)

Author keywords

Alkylidyne; Dimerization; Tungsten

Indexed keywords

ALKYLIDYNE; COMPLEX DIMERIZATION; POTENTIOMETRIC MEASUREMENTS; RING COUPLING;

CATALYSIS; COMPLEXATION; DIMERIZATION; REDOX REACTIONS; REDUCTION; TUNGSTEN; TUNGSTEN COMPOUNDS;

ORGANOMETALLICS;

EID: 33749563342     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.07.029     Document Type: Article

References (23)

1. Bocarsly A.B., Cameron R.E., Rubin H.D., McDermott G.A., Wolff C.R., and Mayr A. Inorg. Chem. 24 (1985) 3976
2. Schoch T.K., Main A.D., Burton R.D., Lucia L.A., Robinson E.A., Schanze K.S., and McElwee-White L. Inorg. Chem. 35 (1996) 7769
3. Da Re R.E., and Hopkins M.D. Coord. Chem. Rev. 249 (2005) 1396
4. Jelliss P.A., Wampler K.M., and Siemiarczuk A. Organometallics 24 (2005) 707
5. Bard A.J., and Faulkner L.R. Electrochemical Methods (1980), Wiley, New York
6. Astruc D. Electron Transfer and Radical Processes in Transition-metal Chemistry (1995), VCH, New York
7. -1). Andrieux C.P., Nadjo L., and Saveant J.M. J. Electroanal. Chem. 42 (1973) 223
8. Forster R.J. Phys. Chem. Chem. Phys. 1 (1999) 1543
9. -3). Adams R.N. Electrochemistry at Solid Electrodes (1969), Marcel Dekker, New York
10. 1/2 (α = 0.5) taken from Ref. [5].
11. Yu M.P.Y., Cheung K.-K., and Mayr A. J. Chem. Soc., Dalton Trans. (1998) 2373
12. Tsai Y.-C., Stephens F.H., Meyer K., Mendiratta A., Gheorghiu M.D., and Cummins C.C. Organometallics 22 (2003) 2902
13. Young C.G., Philipp C.C., White P.S., and Templeton J.L. Inorg. Chem. 34 (1995) 6412
14. Duchateau R., Williams A.J., Gambarotta S., and Chiang M.Y. Inorg. Chem. 30 (1991) 4863
15. De Boer E.J.M., and Teuben J.H. J. Organomet. Chem. 153 (1978) 53
16. Cotton F.A., and Hall W.T. Inorg. Chem. 17 (1978) 3525
17. Finn P.A., King M.S., Kilty P.A., and McCarley R.E. J. Am. Chem. Soc. 97 (1975) 220
18. Grumbine S.D., Chadha R.K., and Tilley T.D. J. Am. Chem. Soc. 114 (1992) 1518
19. McInnes E.J.L., Farley R.D., Rowlands C.C., Welch A.J., Rovatti L., and Yellowlees L.J. J. Chem. Soc., Dalton Trans. (1999) 4203
20. Leelasubcharoen S., Lam K.-C., Concolino T.E., Rheingold A.L., and Theopold K.H. Organometallics 20 (2001) 182
21. Leelasubcharoen S., Lehmann M.W., Theopold K.H., and Evans D.H. J. Electrochem. Soc. 148 (2001) E118
22. Schmidt M.W., Baldridge K.K., Boatz J.A., Elbert S.T., Gordon M.S., Jensen J.J., Koseki S., Matsunaga N., Nguyen K.A., Su S., Windus T.L., Dupuis M., and Montgomery J.A. J. Comput. Chem. 14 (1993) 1347
23. Huzinaga S., Andzelm J., Klobukowski M., Radzio-Andzelm E., Sakai Y., and Tatewaki H. gaussian Basis Sets for Molecular Calculations (1984), Elsevier, Amsterdam