Oxidation of tertiary homoallylic alcohols by thallium trinitrate: Fragmentation vs. ring contraction

Journal of the Brazilian Chemical Society

Volumn 17, Issue 5, 2006, Pages 981-988

  Silva Jr , Luiz F ^a   Quintiliano, Samir A P ^a   Ferraz, Helena M C ^a   Santos, Leonardo S ^b   Eberlin, Marcos N ^b  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

^b UNIVERSITY OF CAMPINAS   (Brazil)

Author keywords

Fragmentation reaction; Homoallylic alcohols; Indan; Ring contraction; Thallium trinitrate

Indexed keywords

EID: 33749556058     PISSN: 01035053     EISSN: 01035053     Source Type: Journal    
DOI: 10.1590/s0103-50532006000500024     Document Type: Article

References (20)

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16. Although 6 equivalents of methyllithium were used in these reactions, the corresponding methyl ketones were always obtained as a byproduct.
17. Ferraz, H. M. C.; Grazini, M. V. A.; Silva Jr., L. F.; Longo Jr., L. S.; Synth. Commun. 1999, 29, 1953.
18. Ferraz, H. M. C.; Aguilar, A. M.; Silva Jr., L. F.; Synthesis 2003, 1031.
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