The unwanted synthesis of (E,£)-4,21-dimethoxy-2,19-dioxahexacycloβOZlS, 13,7, l20,24tetratriacolltan. 3,5,7(35),13,15,17,20,22,24(38),30,32,34,36,39-tetradecaen-12,29dione and other attempts at the synthesis of acerogenins

ACH - Models in Chemistry

Volumn 135, Issue 1-2, 1998, Pages 57-78

  Mihälynö, Grädi ^a   Keserü, Györgym ^a   Kajtar Peredy, Maria ^a   Vermes, Borbala ^a   Nguyen Thu, H A ^a   Dlnya, Zoltan ^a  

^a BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33749313153     PISSN: 12178969     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (26)

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7. An unnatural compound of this type was prepared as an unwanted product in the course of the synthesis of myricanone. WHITING, D. A., WOOD, A. F.: Tetrahedron Lett., 26, 2335 (1978)
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19. BEUGELMANS, R., ZHU, J., HUSSON, N., BOIS-CHOUSSY, M., SINGH, G. P.: J. Chem. Soc. Chem. Commun., 439 (1994)
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24. Enamine 6 formed directly on ring closure of an isoxazole intermediate using a modified Wurtz reaction [3].
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26. In acerogenin C methyl ether e.g. H-20 gives a signal at 5.65 p.p.m., while in garugamblin-1 and -2 the correspoding signals are at 5.27 and 5.20 p.p.m, resp.