The Soret effect in dilute polymer solutions: Influence of chain length, chain stiffness, and solvent quality

Journal of Chemical Physics

Volumn 125, Issue 12, 2006, Pages

  Zhang, Meimei ^a   Müller Plathe, Florian ^a  

^a DARMSTADT UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; SOLVENTS; THERMAL DIFFUSION;

FLEXIBLE POLYMERS; POLYMER SOLUTIONS; RIGID POLYMERS; SORET COEFFICIENT;

POLYMERS;

EID: 33749259560     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2356469     Document Type: Article

References (42)

1. C. Ludwig, Sitzungsber. Preuss. Akad. Wiss., Phys. Math. Kl. 20, 539 (1856).
2. C. Soret, Arch. Sci. Phys. Nat. 3, 48 (1879).
3. D. Reith and F. Müller-Plathe, J. Chem. Phys. 112, 2436 (2000).
4. M. Schimpf and J. Giddings, Macromolecules 20, 1561 (1987).
5. M. Schimpf and J. Giddings, J. Polym. Sci., Part B: Polym. Phys. 27, 1317 (1989).
6. P. Rossmanith and W. Köhler, Macromolecules 29, 3203 (1996).
7. J. Chan, J. J. Popov, S. Kolisnek-Kehl, and D. G. Leaist, J. Solution Chem. 32, 197 (2003).
8. J. Rauch and W. Köhler, J. Chem. Phys. 119, 11977 (2003).
9. M. Giglio and A. Vendramini, Phys. Rev. Lett. 38, 26 (1977).
10. R. Kita, G. Kircher, and S. Wiegand, J. Chem. Phys. 121, 9140 (2004).
11. B. J. de Gans, R. Kita, S. Wiegand, and J. Luettmer-Strathmann, Phys. Rev. Lett. 91, 245501 (2003).
12. B. J. de Gans, R. Kita, B. Müller, and S. Wiegand, J. Chem. Phys. 118, 8073 (2003).
13. J. Luettmer-Strathmann, J. Chem. Phys. 119, 2892 (2003).
14. L. J. Tichacek, W. S. Kmak, and H. G. Drickamer, J. Phys. Chem. 60, 660 (1956).
15. P. Kolodner, H. Williams, and C. Moe, J. Chem. Phys. 88, 6512 (1988).
16. I. Prigogine, L. De Brouckere, and R. Amand, Physica (Amsterdam) 16, 851 (1950).
17. G. Wittko and W. Köhler, J. Chem. Phys. 123, 014506 (2005).
18. B. Rousseau, C. Nieto-Draghi, and J. Bonet Avalos, Europhys. Lett. 67, 247 (2004).
19. S. Wiegand, J. Phys.: Condens. Matter 16, R357 (2004).
20. F. Brochard and P. G. De Gennes, C. R. Acad. Sci., Ser. II: Mec., Phys., Chim., Sci. Terre Univers 293, 1025 (1981).
21. T. N. Khazanovich, J. Polym. Sci., Part C: Polym. Symp. 16, 2463 (1967).
22. M. E. Schimpf and S. N. Semenov, J. Phys. Chem. B 104, 9935 (2000).
23. J. Rauch and W. Köhler, Phys. Rev. Lett. 88, 185901 (2002).
24. F. Müller-Plathe and P. Bordat, in Novel Methods in Soft Matter Simulations, Lecture Notes in Physics Vol. 640, edited by M. Karttunen, I. Vattulainen, and A. Lukkarinen (Springer, Heidelberg, 2004), p. 310.
25. M. Zhang, E. Lussetti, L. E. S. De Souza, and F. Müller-Plathe, J. Phys. Chem. B 109, 15060 (2005).
26. M. Zhang and F. Müller-Plathe, J. Chem. Phys. 123, 124502 (2005).
27. B. Hafskjold, T. Ikeshoji, and S. K. Ratkje, Mol. Phys. 80, 1389 (1993).
28. P. Bordat, D. Reith, and F. Müller-Plathe, J. Chem. Phys. 115, 8978 (2001).
29. G. Galliéro, B. Duguay, J.-P. Caltagirone, and F. Montel, Fluid Phase Equilib. 208, 171 (2003).
30. G. Galliéro, B. Duguay, J.-P. Caltagirone, and F. Montel, Philos. Mag. 83, 2097 (2003).
31. A. Perronace, C. Leppla, F. Leroy, B. Rousseau, and S. Wiegand, J. Chem. Phys. 116, 3718 (2002).
32. J.-M. Simon, D. K. Dysthe, A. H. Fuchs, and B. Rousseau, Fluid Phase Equilib. 150-151, 151 (1998).
33. C. Nieto-Draghi, thesis, Universitat Rovira I Virgili, 2003.
34. R. Faller, F. Müller-Plathe, and A. Heuer, Macromolecules 33, 6602 (2000).
35. F. Müller-Plathe, Comput. Phys. Commun. 78, 77 (1993).
36. H. Schmitz, R. Faller, and F. Müller-Plathe, J. Phys. Chem. B 103, 9731 (1999).
37. H. J. C. Berendsen, J. P. M. Postma, W. F. van Gunsterer, A. Di Nola, and J. R. Haak, J. Chem. Phys. 81, 3684 (1984).
38. M. P. Allen and D. J. Tildesley, Computer Simulation of Liquids (Oxford Science, Oxford, 1987).
39. J. Kumaki, T. Hashimoto, and S. Granick, Phys. Rev. Lett. 77, 1990 (1996).
40. Polymer Handbook, edited by J. Brandrup, E. H. Immergut, and E. A. Grulke (Wiley, New York, 1999).
41. J. Rauch and W. Köhler, Macramolecules 38, 3571 (2005).
42. K. J. Zhang, M. E. Briggs, R. W. Gammon, and J. V. Sengers, J. Chem. Phys. 111, 2270 (1999).