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Besides the mixing of 3dt2 and 4p states of an isolated Mn ion, the crystal field mixes 3dt2 and valence band states. This mixing is responsible for the giant Zeeman effect in DMS and the parameter of the mixing can be found from the value of the hole exchange constant β. The effect of the mixing can be comparable with that of the 3d-4p Mn ion mixing and increases effectiveness of the Auger recombination of bright excitons.
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Besides the mixing of 3dt2 and 4p states of an isolated Mn ion, the crystal field mixes 3dt2 and valence band states. This mixing is responsible for the giant Zeeman effect in DMS and the parameter of the mixing can be found from the value of the hole exchange constant β. The effect of the mixing can be comparable with that of the 3d-4p Mn ion mixing and increases effectiveness of the Auger recombination of bright excitons.
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