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Volumn 33, Issue 15-16, 1994, Pages 1634-1637

Monomer–Dimer Equilibria in Homo‐ and Heterodinuclear Cationic Alkylzirconium Complexes and Their Role in Polymerization Catalysis

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EID: 33749125170     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199416341     Document Type: Article
Times cited : (336)

References (51)
  • 35
    • 84989555647 scopus 로고    scopus 로고
    • 5]pyridine by a single signal at δ = 0.35 (−50°C). The signals at δ = 0.76 and 0.77 remain unchanged on warming, whereas the signal at δ = 0.66 broadens.
  • 36
    • 84989540456 scopus 로고    scopus 로고
    • The stability of dimeric methyl complexes of ansa‐zirconocenes has consequences for the evaluation of the catalytic activity of these species at low temperatures. The stability of 3c and 3d at low temperature suggests that only half as many cationic centers are formed as are expected on the basis of Equation (a).
  • 37
    • 84989518281 scopus 로고    scopus 로고
    • 1H NMR spectrum of 4c at −30°C shows signals for Zr‐Me at δ = −0.47 and −0.61 which broaden on cooling. This finding may be consistent with the presence of solvent and anion adducts of 4c, an unambiguous assignment was, however, not possible.
  • 48
    • 84989532628 scopus 로고    scopus 로고
    • The formation of 5 does not exclude the possibility of Zr‐O coordination like that in 6. It is conceivable, however, that this side reaction may contribute to the deactivation of the catalyst.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.