Simultaneous formation of both novel bis(μ-sulfur)- and bis(μ-oxo)-bridged copper(II) dimers by reaction of N-benzoyl-N′,N′-dimethylthiourea (HL) with CuCl2. Syntheses, crystal structures and magnetic properties of [{CuL(HL)Cl}2] and [{CuL2}2]

Journal of the Chemical Society - Dalton Transactions

Volumn , Issue 16, 1999, Pages 2683-2687

  Che, De Ji ^a   Li, Gang ^a   Yao, Xiao Lan ^a   Yu Zhu, ^a   Zhou, Da Peng ^a  

^a ZHENGZHOU UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33749101118     PISSN: 03009246     EISSN: None     Source Type: Journal    
DOI: 10.1039/a903517f     Document Type: Article

References (22)

1. E. I. Solomon, U. M. Sundaram and T. E. Machonkin, Chem. Rev., 1996, 96, 2563;
2. N. Kilajima and Y. Moro-Oka, Chem. Rev., 1994, 94, 737;
3. K. A. Magnus, H. Ton-that and J. E. Carpenter, Chem. Rev., 1994, 94, 727;
4. E. I. Solomon, M. J. Baldwin and M. D. Lowery, Chem. Rev., 1992, 92, 521;
5. Bioinorganic Chemistry of Copper, eds. K. D. Karlin and Z. Tyeklar, Chapman & Hall, New York, London, 1993;
6. T. G. Spiro, Copper Proteins, Wiley, New York, 1981.
7. W. E. Hatfield, in Magneto structure Correlations in Exchange Coupled Systems, eds. R. D. Willett, D. Gatteschi and O. Kahn, Reidel, Dordrecht, 1985, p. 555;
8. O. Kahn, Angew. Chem., Int. Ed., 1998, 24, 834.
9. D. J. Che, X. L. Yao, G. Li and Y. H. Li, J. Chem. Soc., Dalton Trans., 1998, 1853.
10. R. L. Carlin, Magnetochemistry, Springer, Berlin, Heidelberg, New York, Tokyo, 1986.
11. Y. F. Yuan, L. Y. Zhang, J. P. Cheng and J. T. Wang, Transition Met. Chem., 1997, 22, 281.
12. G. M. Sheldrick, SHELXL 93, Program for refining crystal structures, University of Göttingen, 1993;
13. TEXSAN, Crystal Structure Analysis Package, Molecular Structure Corporation, Houston, TX, 1985 and 1992.
14. O. Seidelman, L. Bayer and R. Richler, Z. Naturforsch., Teil B, 1995, 50, 1679.
15. C. K. Johnson, ORTEP II, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
16. N. Yamazaki and Y. Hohokable, Bull. Chem. Soc. Jpn., 1971, 44, 63.
17. R. M. Silverstein, G. C. Bassler and T. C. Morrill, Spectrometric Identification of Organic Compounds, 4th edn., Wiley, New York, 1981.
18. K. T. McGregor, J. A. Barnes and W. E. Hatfield, J. Am. Chem. Soc., 1973, 95, 7993.
19. S. Sikorov, I. Brouche-Waksman and O. Kahn, Inorg. Chem., 1984, 23, 490.
20. E. C. Constable and P. R. Raithby, J. Chem. Soc., Dalton Trans., 1987, 2281.
21. J. R. Creighton, D. J. Gardiner and A. C. Goruin, Inorg. Chim. Acta, 1985, 103, 195.
22. G. T. Javier, M. K. Urtiaga and R. Cortes, J. Chem. Soc., Dalton Trans., 1994, 2233.