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Angewandte Chemie International Edition in English
Volumn 34, Issue 10, 1995, Pages 1059-1070
Ligand‐Accelerated Catalysis
Author keywords

asymmetric syntheses; catalysis; dihydroxylations; epoxidations; titanium compounds
Indexed keywords

EID: 33748983103     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199510591     Document Type: Review
Times cited : (605)
References (232)
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    • −1 (toluene):, The Scripps Research Institute, unpublished results. Binding constants for the alkaloids DHQ and DHQD are greater in toluene than in tBuOH. The stoichiometric osmylations with bidentate chiral amines [54] are generally run at low temperature in toluene.
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    • (a) The effect of tertiary amine ligands on the catalytic turnover in the original AD process with NMO as the oxidant in a homogeneous acetone/water system is quite different from that seen in the new two‐phase AD process with potassium hexacyanoferrate(III) as the oxidant. In the NMO system, quinuclidine strongly inhibits the catalysis at concentrations above 0.01 M [5a], and even the alkaloid ligands DHQ and DHQD begin to show inhibition at concentrations greater than 0.5 M [5b]. These effects are probably due to “second‐cycle problems” [5b, 57b], which will not be discussed here since they are absent in the now favored potassium hexacyanoferrate(III)‐based AD system.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.