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to be published
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The first X-ray analysis of an in/out-isomer of an amide-based furano[2]catenane was recently obtained: F. Vögtle, S. Ottens-Hildebrandt, T. Schmidt, to be published.
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note
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We have experienced so far that compared to other acid dichlorides 6a leads to the highest yields and the best analytical properties in the formation of rotaxanes.
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44
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33748961855
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note
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Dilute solutions were used to avoid possible shifts of the host/ guest equilibrium by high concentration (activity) of the added reagents (stopper).
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33748969557
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note
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This experiment might be expanded to a combinatorial approach for the one pot-synthesis of families of rotaxanes with varied axles (centre part, stoppers) and wheels.
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