Laboratory-scale iron EDTA-based NOX scrubbing process with biological treatment and regeneration of spent scrubber water

Environmental Engineering Science

Volumn 23, Issue 5, 2006, Pages 788-802

  Dilmore, Robert ^a,b   Neufeld, Ronald D ^a   Hammack, Richard W ^b  

^a PA 15260   (United States)

^b NATIONAL ENERGY TECHNOLOGY LABORATORY   (United States)

Author keywords

Anaerobic treatment; Anoxic treatment; Denitrification; Iron EDTA; Iron reduction; Kinetics; Oxidation reduction potential; Upflow anaerobic bioreactor

Indexed keywords

ABSORPTION; ANAEROBIC DIGESTION; BIOMASS; BIOREACTORS; DENITRIFICATION; ENVIRONMENTAL IMPACT; NITRIDES; REACTION KINETICS; SCRUBBERS;

ANOXIC TREATMENT; IRON EDTA; IRON REDUCTION; OXIDATION REDUCTION POTENTIAL; UPFLOW ANAEROBIC BIOREACTOR;

NITROGEN COMPOUNDS;

ALCOHOL; BIOGAS; EDETATE IRON; NITRATE;

ARTICLE; BIOMASS PRODUCTION; BIOREACTOR; CHEMICAL REACTION; ELECTRON TRANSPORT; LABORATORY; OXIDATION REDUCTION REACTION; SCRUBBER; WASTE WATER MANAGEMENT; WATER TREATMENT;

EID: 33748933053     PISSN: 10928758     EISSN: None     Source Type: Journal    
DOI: 10.1089/ees.2006.23.788     Document Type: Article

References (17)

1. ANDERSON, R.R., and WHITE, C.M. (1994). Analysis of Fischer-Tropsch by-product waters by gas chromatography. J. High Resolut. Chromatogr. 17, 245.
2. AMERICAN PUBLIC HEALTH ASSOCIATION, AMERICAN WATER WORKS ASSOCIATION, WATER ENVIRONMENT FEDERATION. (1998). Standard Methods for the Examination of Water and Waste-water. Washington, DC: Author.
3. BUISMAN, C.J.N., DIJKMAN, H., VERBRAAK, P.L., and DEN HARTOG, A.J. (1999). Process for purifying flue gas containing nitrogen oxides, Biostar Development C.V., U.S. Patent # 6,235,248.
4. BUISMAN, C.J.N., DIJKMAN, H., VERBRAAK, P.L., and DEN HARTOG, A.J. (2001). Apparatus for purifying flue gas containing nitrogen oxides. U.S.A., Biostar Development C.V., U.S. Patent # 5,891,408).
5. X scrubber waters. Ph.D. Dissertation, University of Pittsburgh, School of Engineering, Department of Civil and Environmental Engineering, Pittsburgh, PA.
6. X absorption process. In Water Environment Federation 77th Annual Technical Exhibition & Conference (WEFTEC), New Orleans, LA, October 2-6.
7. X scrubbing process waters. In 96th Annual Conference and Exposition of the Air and Waste Management Association: Environment in the Balance, San Diego, CA, June 25 (Paper # 69807).
8. X Removal in Wet Scrubbers Using Metal Chelates, Final Report Volumes 1 and 2. Prepared for the U.S. Department of Energy Pittsburgh Energy Technology Center, Submitted by Dravo Lime Company.
9. ENGELMANN, M.D., BOBIER, R.T., HIATT, T., and CHENG, I.F. (2003). Variability of the Fenton reaction characteristics of the EDTA, DTPA, and citrate complexes of iron. BioMetals 16, 519.
10. KLEIFGES, K.H., JUZELIUNAS, E., and JUTTNER, K. (1997). Electrochemical study of direct and indirect NO reduction with complexing agents and redox mediator. Electrochem. Acta 32, 2947.
11. X Aqueous Scrubber System. Argonne National Laboratory/University of Cincinatti.
12. PERRY, R.H., GREEN, D.W., and MALONEY, J.O., Eds. (1997). Perry's Chemical Engineers' Handbook, 7th ed. New York: McGraw-Hill, Inc.
13. 3 with Fe(II)-EDTA. Indust. Eng. Chem. Process Des. Dev. 19, 377.
14. 3. Ind. Eng. Chem. Fundam. 23, 60.
15. SAITO, T., SEKIYA, T., et al. (1976). Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas. U.S.A., Asahi Chemical Industry Co., Ltd.. (formerly Asahi Kasei Kogyo Kabushiki Kaisha) (Osaka, JA) U.S. Patent #3,984,522.
16. VAN DER MAAS, P., WEELINK, S., et al. (2002). BioDeNOx: Fe-EDTA as electron mediator between denitrification and iron reduction. In Annual Conference of the Air & Waste Management Association, Baltimore, MD.
17. VAN DER MAAS, P., VAN DE SANDT, T., KLAPWIJK, B., and LENS, P. (2003). Biological reduction of nitric oxide in aqueous Fe(II)EDTA solutions. Biotechnol. Prog. 19, 1323.