Synthesis, spectra, structure and quantum chemistry study on two novel oxovanadium complexes with hydrotris (pyrazolyl) borate ligands

Chinese Science Bulletin

Volumn 51, Issue 6, 2006, Pages 661-667

  Xing, Yongheng ^a   Sun, Zheng ^b   Yuan, Houqun ^a   Ge, Maofa ^b   Niu, Shuyun ^a   Bai, Fengying ^a  

^a LIAONING NORMAL UNIVERSITY   (China)

^b INSTITUTE OF CHEMISTRY   (China)

Author keywords

Crystal structure; Oxovanadium complexes; Quantum calculation; Spectrum; Tris(pyrazolyl)hydroborate

Indexed keywords

EID: 33748909192     PISSN: 10016538     EISSN: 18619541     Source Type: Journal    
DOI: 10.1007/s11434-006-0661-z     Document Type: Article

References (20)

1. Plass, W., Supermolecular interactions of vanadate species: vanadium(V) complexes with N-salicylidenehydrazides as versatile models, Coord. Chem. Rev., 2003, 237: 205-212.
2. Crans, D. C., Smee, J. J., Gaidamauskas, E. et al., The chemistry and biochemistry of vanadium and the biological activities exerted by vanadium compounds, Chem. Rev., 2004, 104: 849-902.
3. Shechter, Y., Insulin-mimetic effects of vanadate, Diabetes, 1990, 39: 1-5.
4. - and thiamine mono- and diphosphate, Journal of Inorganic Biochemistry, 1999, 75:303-309.
5. Crans, D. C., Keramidas, A. D., Amin, S. S. et al., Six-co-ordinated vanadium-(IV) and -(V) complexes of benzimidazole, J. Chem. Soc., Dalton trans., 1997, 2799-2712.
6. Rehder, D., Pessoa, J. C., Geraldes, C. F. G C. et al., In vitro study of the insulin-mimetic behaviour of vanadium (IV, V) coordination compounds, J. Biol. Inorg. Chem., 2002, 7: 384-396.
7. Thompson, K. H., Orvig, C., Coordination chemistry of vanadium in metallopharmaceutical candinate compounds, Coord. Chem. Rev., 2001, 219-221: 1033-1053.
8. Trofimenko, S., Scorpionates, the Coordination Chemistry of Polypyrazolylborate Ligands, University of Delaware, Newark, DE, USA: Imperial College Press, 1999.
9. Issigoni, M., Katsaros, N., Vrachnou-Astra, E. et al., Pyrazole and imidazole complexes of vanadium chloride, Inorg. Chim. Acta, 1974, 9:131-135.
10. Zofia, K., Studies of the structure of vanadium (III) complexes with nitrogen containing ligands in alcoholic solutions. I. complexes of V(III) with azoles, J. Coord. Chem., 1979, 9: 37-41.
11. Leslie, F. L., Michael, O.W., Ethanolates and heterocyclic amine complexes of vanadium (II), Inorganica Chimica Acta, 1983, 71: 81-86.
12. Carrano, C. J., Mohan, M., Holmes, S. M. et al., Oxovanadium (V) alkoxo-chloro complexes of the hydridotripyrazoly; borates as models for the binding site in bromoperoxidase, Inorg. Chem., 1994, 33:646-655.
13. Collison, D., Eardley, D. R., Mabbs, F. E. et al., Synthesis, crystallographic and spectroscopic characterization, and magnetic properties of mixed-ligand oxovanadium (IV) hydrotris(3,5-dimethylpyrazolyl)borate complexes, Inorganic Chemistry, 1993, 32(5): 664-671.
14. Kime-Hunt, E., Spartalian, K., Derusha, M. et al., Synthesis, characterization, and molecular structures of a series of [(3,5- dimethylpyrazolyl)borato]vanadium (III) and -(IV) complexes, Inorg. Chem., 1989, 28: 4392-4399.
15. Herberhold, M., Frohmader, G., Hofmann, T. et al., Synthesis and characterization of new hydrotri(3,5-dimethyl-1-pyrazolyl)borate vanadium halfsanwich complexes, Inorg. Chim. Acta, 1998, 267: 19-25.
16. Trofimenko, S., Boron-pyrazole chemistry. II. Poly(1-pyrazolyl) borates, J. Am. Chem. Soc., 1967, 89: 3170-3177.
17. Trofimenko, S., Calabrese, J. C., Thompson, J. S., Novel polypyrazolyl borate ligands: Coordination control through 3-sub-stituents of the pyrazole ring, Inorg. Chem., 1987, 26:1507-1514.
18. Sheldrick, G M., SHELXL97. Program for the refinement of crystal structures, University of Göttingen, Germany, 1990.
19. Liu, J. C., Guo, G C., Huang, J. S. et al., Different oxidation states of copper (I, I/II, II) Thiocyanate complexes containing 1,2,4-triazole as a bridging ligand: Syntheses, crystal structures, and magnetic properties of 2-D polymer Cu'(admtrz)SCN, linear trinuclear [CuI2CuIII(admtrz)6(SCN)2](ClO4)2, and triangular trinuclear [CuII3(admtrz)4(SCN)3(μ3-OH)(H2O)2](ClO4)2.H2O(admtrz= 4-amino-3,5-dimethyl-1,2,4-triazole), Inorg. Chem., 2003, 42: 235-243.
20. Freire, E., Baggio, S., Suescun, L. et al., Comparative X-ray study of three Nickel(II)-thiocyanate compounds, Acta Crystallographica Section C, 2001, C57: 905-908.