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Volumn 16, Issue 6, 1977, Pages 339-348

Recent Applications of α‐Metalated Isocyanides in Organic Synthesis

Author keywords

Isocyanides; Synthetic methods; Metalated isocyanides

Indexed keywords

CHEMICAL REACTIONS;

EID: 33748903783     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.197703393     Document Type: Review
Times cited : (220)

References (118)
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    • Umpolung der Reaktivität von Aminen. Nucleophile α-sek.-Aminoalkylierung über metallierte Nitrosamine
    • Concerning this problem and previous attempts to solve it
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  • 13
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    • Über Darstellung und Umsetzungen von Formamidomethyl-aminen, -sulfiden und -sulfonen
    • (b) with phosphorus oxide chloride
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  • 20
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    • N‐alkylformamides are obtained either by formylation of amines or (in the case of allyl compounds) from the halides by treatment with N‐sodioformamide in acetonitrile; numerous applications are listed in 8, 59.
  • 32
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    • Cf. 5a, footnote 67.
  • 43
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    • van Leusen et al. proposed the abbreviation “Tosmic” for 19.
  • 54
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    • Synthesen mit α-metallierten Isocyaniden, XXV. 4-Cyan-2-isocyanalkansäure-äthylester, 4-Cyan-2-(formylamino)alkansäure-äthylester und 4-Cyan-5(4)-pyrrolin-2-carbonsäure-äthylester aus α-metallierten Isocyanalkansäure-äthylestern und Acrylnitrilen
    • (1973) Chemische Berichte , vol.106 , pp. 3382
    • Schöllkopf, U.1    Porsch, P.‐H.2
  • 62
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    • For the acylimidazoline method, see, Dissertation, Universität Göttingen 1977.
    • Henneke, K.‐W.1
  • 67
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    • Neuere Methoden der präparativen organischen Chemie IV Synthesen mit heterocyclischen Amiden (Azoliden)
    • (1962) Angewandte Chemie , vol.74 , pp. 407
    • Staab, H.A.1
  • 70
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    • Obtainable by reaction of 17a in tetrahydrofuran at −55°C with 0.5 equiv. of butyllithium. Cf., Dissertation, Universität Göttingen
    • (1973)
    • Jentsch, R.1
  • 74
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    • Dissertation, Universität Göttingen 1975.
    • Harms, R.1
  • 76
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    • Diplomarbeit, Universität Göttingen 1976, Dissertation, Universität Göttingen, planned for 1978.
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  • 78
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    • Cf. 11;, Dissertation, Universität Göttingen 1973.
    • Hantke, K.1
  • 82
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    • 1,3-Dipolar cycloadditions. 76. Concerted nature of 1,3-dipolar cycloadditions and the question of diradical intermediates
    • earlier references cited therein
    • (1976) The Journal of Organic Chemistry , vol.41 , pp. 403
    • Husigen, R.1
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    • Diplomarbeit, Universität Göttingen 1977.
    • Lau, H.‐H.1
  • 92
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    • Justus Liebigs Ann. Chem.1977, in press; that paper describes the addition of Grignard compounds 32 to tert‐alkyl‐substituted glycines.
    • Schöllkopf, U.1    Meyer, R.2
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    • Dissertation, Universität Göttingen 1976.
    • Czempik, K.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.