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Volumn 33, Issue 4, 1994, Pages 385-415

Organic and Organometallic Molecular Magnetic Materials—Designer Magnets

Author keywords

Magnetic properties; Organic magnets

Indexed keywords


EID: 33748886713     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199403851     Document Type: Review
Times cited : (1487)

References (260)
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    • Generally three‐dimensional interactions are necessary; however, in some circumstances two‐dimensional and even one‐dimensional interactions for alternating quantum (S = 1/2) and classical (S > 1/2) spins, hysteretic effects can occur. See for example
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    • Since as described earlier J ∝ 1/ΔE AB′ij and since instead of the POMOs being involved in the charge‐transfer excitation, the excitation involves the NHOMO and/or NLUMO; thus, the ΔE will be greater and J will be smaller.
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    • 2) a range of x and y is observed for preparations in different solvents and with different mole ratios of the starting materials; benzene in small amounts is present in some cases. For the material discussed herein x ≈ 2; Y ≈ 1/2. Trace elements were determined by ICP: (Fe 41 ppm), Co [none detected (<25 ppm)], Ni [none detected (50 ppm)], (Cr 34 ppm).


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