Experimental 300 K measurement of the rate constant of the reaction OH + BrO → products

Journal of Physical Chemistry

Volumn 100, Issue 34, 1996, Pages 14383-14389

  Bogan, Denis J ^a,b,c   Peyton Thorn, R ^a,b   Nesbitt, Fred L ^a,d   Stief, Louis J ^a  

^a NASA GODDARD SPACE FLIGHT CENTER   (United States)

^b CATHOLIC UNIVERSITY OF AMERICA   (United States)

^c NAS/NRC ^*

^d Criminal Justice and Applied Social and Political Sciences Department   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33748863817     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9608077     Document Type: Article

References (21)

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12. + in panel d. For example, if m/z = 97 in panel d were 15% of m/z = 98, then 15% of the m/z = 98 signal of panel c should be subtracted from the m/z = 97 signal of panel c. This approach was tried and found to be unsatisfactory because the fragmentation ratio (m/z = 97):(m/z = 98) from HOBr was not stable and in some cases its use led to negative values of [BrO]. In contrast, the intensity of m/z = 97 was always greater in panel c than in panel b, so that values of [BrO] derived as explained in the text were always positive and credible.
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