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Volumn 128, Issue 37, 2006, Pages 12192-12204

Pentacyanoiron(II) as an electron donor group for nonlinear optics: Medium-responsive properties and comparisons with related pentaammineruthenium(II) complexes

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; CYCLIC VOLTAMMETRY; ELECTRONIC PROPERTIES; NONLINEAR OPTICS; ORGANIC SOLVENTS; RUTHENIUM COMPOUNDS;

EID: 33748858355     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja063449m     Document Type: Article
Times cited : (64)

References (96)
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    • (g) Shi, S. In Optoelectronic Properties of Inorganic Compounds; Roundhill, D. M.; Fackler, J. P., Jr., Eds.; Plenum: New York, U.S.A., 1999; pp 55-105.
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    • Shi, S.1
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    • McCleverty, J. A., Meyer, T. J., Eds.; Elsevier Pergamon: Oxford, U.K.
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    • (2004) Comprehensive Coordination Chemistry II , vol.9 , pp. 621-687
    • Coe, B.J.1
  • 59
    • 0004150157 scopus 로고    scopus 로고
    • Bruker AXS. Inc.; Madison. WI
    • SHELXTL (Version 6.10); Bruker AXS. Inc.; Madison. WI, 2000.
    • (2000) SHELXTL (Version 6.10)
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    • 0001269334 scopus 로고
    • Lim, E. C., Ed.; Academic Press: New York
    • (a) Liptay, W. In Excited States; Lim, E. C., Ed.; Academic Press: New York, 1974; Vol. 1, pp 129-229.
    • (1974) Excited States , vol.1 , pp. 129-229
    • Liptay, W.1
  • 71
    • 0000189651 scopus 로고
    • The B3P86 Functional consists of Becke's three-parameter hybrid functional (Becke, A. D. J. Chem. Phys. 1993, 98, 5648-5652)
    • (1993) J. Chem. Phys. , vol.98 , pp. 5648-5652
    • Becke, A.D.1
  • 72
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    • with the nonlocal correlation provided by the Perdew 86 expression: Perdew, J. P. Phys. Rev. B 1986, 33, 8822-8824.
    • (1986) Phys. Rev. B , vol.33 , pp. 8822-8824
    • Perdew, J.P.1
  • 94
    • 33748851350 scopus 로고    scopus 로고
    • note
    • 5) group by using B3P86/6-311+G* are as follows. Anion in 1. gas phase -1.844; PCM-(water) -2.859. Anion in 5, gas phase -1.826; PCM(water) -2.935. These results are consistent with the iron atom having a formal oxidation state of +3 in the gas phase and +2 in water.
  • 95
    • 33748862235 scopus 로고    scopus 로고
    • note
    • 1H NMR spectra and CHN analyses), there is no reason to doubt the chromophoric purity of 7-12. However, for the purposes of calculating the solution concentrations for physical studies, we make the assumption that all of these samples contain 3 molar equivalents of water of crystallization.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.