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Volumn 39, Issue 18, 2006, Pages 5971-5973

C - H to O hydrogen bonding: The attractive interaction in the blend between polystyrene and poly(vinyl methyl ether)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC HYDROGEN; HYBRIDIZATION DEPENDENCE; MAGIC ANGLE SPINNING (MAS); SOLUTION CASTING;

EID: 33748808967     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma061376l     Document Type: Article
Times cited : (15)

References (35)
  • 11
    • 33748758859 scopus 로고    scopus 로고
    • note
    • The molecular weights (kg/mol) of the three deuterated polystyrenes, ortho, meta, and para, were 124, 106, and 120, respectively, as determined by gel permeation chromatography. Small-angle light scattering cloud point determinations were made for the blends of the monodeuterated samples, which showed small increases of between 5 and 6 °C in the LCST of the blend over that observed for hydrogenous PS. The LCST results were higher for the meta and para over the ortho deuterated samples. We thank Professor Nitash Balsara for this effort conducted at the Polytechnic University.
  • 23
    • 79960671011 scopus 로고    scopus 로고
    • See ref 1, section 2.2, p 40 ff and references therein
    • See ref 1, section 2.2, General Properties, p 40 ff and references therein.
    • General Properties
  • 25
    • 33748787580 scopus 로고    scopus 로고
    • See ref 1, pp 29-40
    • See ref 1, pp 29-40.
  • 27
    • 25844432337 scopus 로고    scopus 로고
    • For the most recent references to this large literature and related literature with leading references to this growing field, see: (a) Solà, J.; Riera, A.; Verdaguer, X.; Maestro, M. A. J. Am. Chem. Soc. 2005, 127, 13629-13633.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 13629-13633
    • Solà, J.1    Riera, A.2    Verdaguer, X.3    Maestro, M.A.4
  • 32
    • 15244358461 scopus 로고    scopus 로고
    • Weak hydrogen bonds to carbon bound hydrogen have now been recognized for their importance in the polymer literature: Zhang, J.; Sato, H.; Tsuji, J.; Noda, I.; Ozaki, Y. Macromolecules 2005, 38, 1822.
    • (2005) Macromolecules , vol.38 , pp. 1822
    • Zhang, J.1    Sato, H.2    Tsuji, J.3    Noda, I.4    Ozaki, Y.5
  • 33
    • 6744266061 scopus 로고
    • For one kind of example where the cooperation-amplification characteristics of polymers allowed insight into effects difficult to discern in small molecules and as well another example of a structural isotope effect in polymers, see: (a) Green, M. M.; Peterson, N. C.; Sato, T.; Teramoto, A.; Lifson, S. Science 1995, 268, 1860.
    • (1995) Science , vol.268 , pp. 1860
    • Green, M.M.1    Peterson, N.C.2    Sato, T.3    Teramoto, A.4    Lifson, S.5
  • 35
    • 0004228599 scopus 로고
    • Wiley-Interscience: New York
    • This philosophy drove Herman Mark to organize the Polymer Research Institute at Brooklyn Poly to be closely connected to the chemistry department and is a central idea found in: Morawetz, H. Macromolecules in Solution, 2nd ed.; Wiley-Interscience: New York, 1975.
    • (1975) Macromolecules in Solution, 2nd Ed.
    • Morawetz, H.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.