Gas-phase conversion of acetone to methyl isobutyl ketone over bifunctional metal/carbon catalysts. 2. Examination of the hydrogenation potential of different metals

Industrial and Engineering Chemistry Research

Volumn 45, Issue 18, 2006, Pages 6111-6117

  Waters, Gerrit ^a   Richter, Oliver ^a   Kraushaar Czarnetzki, Bettina ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CATALYSTS; COSTS; HYDROGENATION; KETONES; STOICHIOMETRY;

BERTY REACTOR; CARBINOL; GAS-PHASE CONVERSION;

ACETONE;

ACETONE; CATALYST ACTIVITY; CATALYSTS; COSTS; HYDROGENATION; KETONES; STOICHIOMETRY;

EID: 33748795795     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0601854     Document Type: Article

References (25)

1. Guisnet, M.; Mitschker, A.; Wagner, R.; Lange, P. M. Heterogeneous Catalysis and Fine Chemicals; Elsevier Science Publishers: New York, 1988.
2. Di Cosimo, J. I.; Torres, G.; Apesteguia, C. R. One-Step MIBK Synthesis: A New Process from 2-Propanol. J. Catal. 2002, 208, 114-123.
3. Melo, L.; Giannetto, G.; Alvarez, F.; Magnoux, P.; Guisnet, M. Effect of the metallic/acid site (nPt/nA) ratio on the transformation of acetone towards methyl isobutyl ketone. Catal. Lett. 1997, 44, 201-204.
4. Melo, L.; Giannetto, G.; Cardozo, L.; Llanos, A.; Garcia, L.; Magnoux, P.; Guisnet, M.; Alvarez, F. Acetone transformation into methyl isobutyl ketone over Pt/HMFI catalysts. IV. Effect of density and strength of the acidic sites. Catal. Lett. 1999, 60, 217-222.
5. Melo, L.; Llanos, A.; Garcia, L.; Magnoux, P.; Alvarez, F.; Guisnet, M.; Giannetto, G. Synthesis of methyl isobutyl ketone using Pt-H[Al]ZSM5 bifunctional catalysts. III. effect of the nPt/nA parameter on the xPt-H[Al]-ZSM5(y) catalysts. Catal. Lett. 1998, 51, 207-212.
6. Yang, S. M.; Wu, Y. M. One step synthesis of methyl isobutyl ketone over palladium supported on AlPO4-11 and SAPO-11. Appl. Catal. A: Gen. 2000, 192, 211-220.
7. Gandia, L. M.; Malm, R.; Marchand, R.; Conanec, R.; Laurent, Y.; Montes, M. Application of a new hydrogenated aluminophosphate oxynitride (ALPON) as a catalytic support for the one-step synthesis of methyl isobutyl ketone from acetone. Appl. Catal. A: Gen. 1994, 114, L1-L7.
8. Melo, L.; Velasquez, D.; Llanos, A.; Garcia, L.; Giannetto, G.; Guisnet, M.; Magnoux, P.; Alvarez, F. Acetone transformation over PtCu/H[Al]ZSM5 catalysts. Effect of copper content. Catal. Lett. 2002, 78, 57-63.
9. Mattos, L. V.; Noronha, F. B.; Monteiro, J. L. F. Bifunctional Metal/ Base Catalysts (Pt/X) for the Direct Synthesis of MIBK from Acetone. J. Catal. 2002, 209, 166-176.
10. Das, N.; Tichit, D.; Durand, R.; Graffin, P.; Coq, B. Influence of the metal function in the "one-pot" synthesis of 4-methyl-2-pentanone (methyl isobutyl ketone) from acetone over palladium supported on Mg-(Al)O mixed oxide catalysts. Catal. Lett. 2001, 71, 181-185.
11. Coh, B. Y.; Cho, K. H.; Lee, H. I. Preparation of high-surface-area Ni/CaO catalyst with citric acid and its application to MIBK synthesis. J. Chem. Eng. Jpn. 2001, 34, 138-142.
12. Chikan, V.; Molnar, A.; Balazsik, K. One-Step Synthesis of Methyl Isobutyl Ketone from Acetone and Hydrogen over Cu-on-MgO Catalysts. J. Catal. 1999, 184, 134-143.
13. Varga, M.; Molnar, A.; Mulas, G.; Mohai, M.; Bertoti, I.; Cocco, G. Cu-MgO Samples Prepared by Mechanochemistry for Catalytic Application. J. Catal. 2002, 200, 71-81.
14. Lin, K. H.; Ko, A. N. Low-pressure one-step synthesis of methyl isobutyl ketone from acetone and hydrogen over metal modified solid base catalysts. J. Chin. Chem. Soc. 2002, 49, 935-942.
15. Lin, K. H.; Ko, A. N. Na promotion of Pd/MgO catalysts for low-pressure one-step synthesis of MIBK from acetone + H2. Appl. Catal. A: Gen. 1996, 147, L259-L465.
16. Chen, Y. Z.; Hwang, C. M.; Liaw, C. W. One-step synthesis of methyl isobutyl ketone from acetone with calcined Mg/Al hydrotalcite-supported palladium or nickel catalysts. Appl. Catal. A: Gen. 1998, 169, 207-214.
17. Gandia, L. M.; Montes, M. Highly selective one-step formation of methyl isobutyl ketone from acetone with a magnesia supported nickel catalyst. Appl. Catal. A: Gen. 1993, 101, L1-L6.
18. Waters, G.; Richter O.; Kraushaar-Czarnetzki, B. Gas-phase conversion of acetone to MIBK over bifunctional metal/carbon catalysts (I): investigation of the acid-base sites. Ind. Eng, Chem. Res., published online July 8, http://dx.doi.org/10.1021/ie060184b.
19. Goguet, A.; Schweich, D.; Candy, J. P. Preparation of a Pt/SiO2 catalyst II. Temperature-programmed decomposition of the adsorbed platinum tetrammine hydroxide complex under flowing hydrogen, oxygen, and argon. J. Catal. 2003, 220, 280-290.
20. Bonivardi, A. L.; Baltanas, M. A. Preparation of palladium/silica catalysts for methanol synthesis. II. Thermal decomposition of tetraamminepalladium(II)/silica. Thermochim. Acta 1991, 191, 63-94.
21. Wang, S.; Lu, G. Q. Effects of Oxide Promoters on Metal Dispersion and Metal-Support Interactions in Ni Catalysts Supported on Activated Carbon. Ind. Eng. Chem. Res. 1997, 36, 5103-5109.
22. Taylor, T. J.; Dollimore, D.; Gamlen, G. A. Deaquation and denitration studies on copper nitrate trihydrate. Thermochim. Acta 1986, 103, 333-340.
23. Fuente, A. M.; Pulgar, G.; Gonzalez, F.; Pesquera, C.; Blanco, C. Activated carbon supported Pt catalysts: effect of support texture and metal precursor on activity of acetone hydrogenation. Appl. Catal. A: Gen. 2001, 208, 35-46.
24. Noh, J. S.; Schwarz J. A. Estimation of the point of zero charge of simple oxides by mass titration. J. Colloid Interface Sci. 1989, 130, 157-163.
25. Menendez, J. A.; Phillips, J.; Xia, B.; Radovic, L. R.; Ljubisa, R. On the Modification and Characterization of Chemical Surface Properties of Activated Carbon: In the Search of Carbons with Stable Basic Properties. Langmuir 1996, 12, 4404-4410.