Photoinduced electron transfer from tetrasulfonated porphyrin to benzoquinone revisited. The structural volume-normalized entropy change correlates with marcus reorganization energy

Journal of Physical Chemistry A

Volumn 110, Issue 34, 2006, Pages 10185-10190

  Andrés, Gabriel O ^a   Martínez Junza, Víctor ^a   Crovetto, Luis ^a   Braslavsky, Silvia E ^a  

^a MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CORRELATION METHODS; ELECTRON ENERGY LEVELS; ENTROPY; NITROGEN COMPOUNDS; PHOTOACOUSTIC EFFECT; PORPHYRINS; QUENCHING;

ELECTRON-TRANSFER (ET) QUENCHING; FREE RADICALS FORMATION; LASER-INDUCED OPTOACOUSTIC SPECTROSCOPY; PHOTOINDUCED ELECTRON TRANSFER;

ELECTRON TRANSITIONS;

BENZOQUINONE; BENZOQUINONE DERIVATIVE; FREE RADICAL; MESO TETRAKIS(4 SULFONATOPHENYL)PORPHYRIN; MESO-TETRAKIS(4-SULFONATOPHENYL)PORPHYRIN; PORPHYRIN;

ARTICLE; BIOLOGICAL MODEL; CHEMISTRY; ELECTRON TRANSPORT; ENTROPY; PHOTOCHEMISTRY; QUANTUM THEORY; TEMPERATURE; THERMODYNAMICS;

BENZOQUINONES; ELECTRON TRANSPORT; ENTROPY; FREE RADICALS; MODELS, BIOLOGICAL; PHOTOCHEMISTRY; PORPHYRINS; QUANTUM THEORY; TEMPERATURE; THERMODYNAMICS;

EID: 33748794771     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp062579e     Document Type: Article

References (36)

1. Meyer, T. J. Acc. Chem. Res. 1989, 22, 163-170.
2. Gust, D.; Moore, T. A.; Moore, A. L. Acc. Chem. Res. 1993, 26, 198-205.
3. Gust, D.; Moore, T. A.; Moore, A. L. Acc. Chem. Res. 2001, 34, 40-48.
4. Pekkarinen, L.; Linschitz, H. J. Am. Chem. Soc. 1960, 82, 2407-2411.
5. Amao, Y.; Tomonou, Y.; Okura, I. Solar Energy Solar Cells 2003, 79, 103-111.
6. Marcus, R. A. J. Chem. Phys. 1956, 24, 966-978.
7. Gensch, T.; Viappiani, C.; Braslavsky, S. E. In Encyclopedia of Spectroscopy and Spectrometry; Lindon, J. C., Tranter, G. E., Holmes, J. L., Eds.; Academic Press: New York, 1999; pp 1124-1132.
8. Losi, A.; Braslavsky, S. E. Phys. Chem. Chem. Phys. 2003, 5, 2739-2750.
9. Borsarelli, C. D.; Braslavsky, S. E. J. Phys. Chem. B 1998, 102, 6231-6238.
10. Borsarelli, C. D.; Braslavsky, S. E. J. Phys. Chem. A 1999, 103, 1719-1727.
11. Yeow, E. K. L.; Slep, L. D.; Chibisov, A. K.; Braslavsky, S. E. J. Phys. Chem. A 2003, 107, 439-446.
12. Yeow, E. K. L.; Braslavsky, S. E. Phys. Chem. Chem. Phys. 2002, 4, 239-247.
13. Crovetto, L.; Martínez-Junza, V.; Braslavsky, S. E. Photochem. Photobiol. 2006, 82, 281-290.
14. Gensch, T.; Viappiani, C.; Braslavsky, S. E. J. Am. Chem. Soc. 1999, 121, 10573-10582.
15. Feitelson, J.; Mauzerall, D. J. Phys. Chem. 1996, 100, 7698-7703.
16. Gensch, T.; Braslavsky, S. E. J. Phys. Chem. 1997, 101, 101-108.
17. Schmidt, P.; Gensch, T.; Remberg, A.; Gärtner, W.; Braslavsky, S. E.; Schaffner, K. Photochem. Photobiol. 1998, 68, 754-761.
18. Bensasson, R. V.; Land, E. J.; Truscott, T. G. Excited State and Free Radicals in Biology and Medicine; Oxford University Press: Oxford, U.K., 1993.
19. Kubat, P.; Mosinger, J. J. Photochem. Photobiol. A 1996, 96, 93-97.
20. Kalyanasudaram, K.; Neumann-Spallart, M. J. Phys. Chem. 1982, 86, 5163-5169.
21. Nahor, G. S.; Rabani, J.; Grieser, F. J. Phys. Chem. 1981, 85, 697-702.
22. Braslavsky, S. E.; Heibel, G. E. Chem. Rev. 1992, 92, 1381-1410.
23. Gensch, T.; Viappiani, C. Photochem. Photobiol. Sei. 2003, 2, 699-721.
24. Losi, A.; Yruela, I.; Reus, M.; Holzwarth, A. R.; Braslavsky, S. E. Photochem. Photobiol. Sci. 2003, 2, 722-729.
25. Rudzki-Small, J.; Libertini, L. J.; Small, E. W. Biophys. Chem. 1992, 42, 29-48.
26. Marcus, R. A.; Sutin, N. Biochim. Biophys. Acta 1985, 811, 265-322.
27. Crovetto, L.; Braslavsky, S. E. J. Phys. Chem. A 2006, 110, 7307-7315.
28. Losi, A.; Wegener, A. A.; Engelhard, M.; Braslavsky S. E. J. Am. Chem. Soc. 2001, 123, 1766-1767.
29. Grunwald, E.; Comeford, L. L. In Protein-Solvent Interactions; Gregory, R. B., Ed., Marcel Dekker: New York, 1995; pp 421-443.
30. Liu, L.; Guo, Q. Y. Chem. Rev. 2001, 101, 673-695.
31. Marcus, Y. Ion Solvation; John Wiley & Sons: New York, 1985.
32. Wardman, P. J. Phys. Chem. Ref. Data 1989, 18, 1637-1755.
33. -1 was used for the calculation.
34. 27 the inequality describing this situation was wrongly written).
35. Togashi, D. M.; Costa, S. M. B. New J. Chem. 2002, 26, 1774-1783.
36. Dutt, G. B.; Periasamy, N. J. Chem. Soc., Faraday Trans. 1991, 87, 3815-3820.