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33748734970
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2 has been used for the selective triple acylation of tetrahydroxy-para-tert-butyl calix[4]arene. However, this base was not suitable for a selective acylation with n-butyl isocyanate.
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33748716265
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Triply acylated calixarenes have been isolated in small yields from the reaction with acyl chlorides. See ref.[5]
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[7f] Triply acylated calixarenes have been isolated in small yields from the reaction with acyl chlorides. See ref.[5]
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36
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33748716948
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note
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[8b] The cocrystallisation of 1 and 3 with alkalimetal salts under various conditions were not successful.
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38
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0001937784
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(Eds.: J.-M. Lehn, J. L. Atwood, J. E. D. Davies, D. D. Macnicol, F. Vögtle, D. N. Reinhoudt), Pergamon, Oxford
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33748737069
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unpublished results
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[10a] In competitive salt extraction experiments or ion transport experiments a source phase containing several nitrate salts is used. The salt content of the receiving phase (or the extracted aqueous phase) is analyzed by inductively coupled plasma atom emission spectroscopy (ICP-AES). This procedure allows the investigation of the transport pattern of a compound under given conditions in a single experiment. B. König, M. Bahadir, M. Müller, H. Wichman, unpublished results.
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47
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33748733739
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note
-
As in the case of the smaller calixarene carbamates, 6 and 7 show intensive molecular ions of their alkali metal complexes in mass spectra. Their transport ability was tested in membrane transport of metal salts giving no significant activity.
-
-
-
-
48
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0001788260
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A solution of 3 in acetone was refluxed to investigate a possible catalysis of the aldol reaction under neutral conditions. However, GC analysis showed that no additional aldol addition product was formed under these conditions. For a recent example of the use of calixarenes as catalysts see: N. Pirrincioglu, F. Zaman, A. Williams, J. Chem. Soc., Perkin Trans. 2 1996, 2561-2562.
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33748739784
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note
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-1.
-
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50
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33748720310
-
-
note
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The calculations were performed independently without the use of experimental data.
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51
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0024821263
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