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Volumn 1, Issue 1-2, 2006, Pages 76-81

Countercation transport modeled by porous spherical molybdenum oxide based nanocapsules

Author keywords

Ion channels; Ion transport; Molybdenum; Nanocapsules; NMR spectroseopy; Polyoxometalates

Indexed keywords

CATION; MOLYBDENUM; NANOPARTICLE; OXIDE;

EID: 33748665976     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200600035     Document Type: Article
Times cited : (22)

References (36)
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    • and Corrigendum
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    • [3a] The uptake of the externally added cations is favored if its solvation/hydration enthalpy is not too large, whereas the uptake becomes disfavored as an increasing number of new cations is incorporated, because this leads to a decrease in the electrochemical gradient (the sum of the concentration and the electric gradient). For counterion transport, the contribution of the first term should be larger. However, examples of capsules in which the cavity contains only water are also known, because the counterions, such as those of the guanidinium type, are too large to enter. In those cases, the electric gradient should also change dramatically during cation uptake; see: A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, S. Roy, A. Berkle, Angew. Chem. 2002, 114, 3756-3761;
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    • Müller, A.1    Krickemeyer, E.2    Bögge, H.3    Schmidtmann, M.4    Roy, S.5    Berkle, A.6
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    • For the cellular mechanisms of cation transport, see, for example: G. R. Dubyak, Advan. Physiol. Edu. 2004, 28, 143-154.
    • (2004) Advan. Physiol. Edu. , vol.28 , pp. 143-154
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    • note
    • See reference [4]. In that paper, the interaction of the encapsulated cations with water molecules is discussed; this interaction also has an influence on the differences of the Gibbs energies mentioned in the Introduction.
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    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 5039-5044
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    • Angew. Chem. Int. Ed. 2005, 44, 7757-7761.
    • (2005) Angew. Chem. Int. Ed. , vol.44 , pp. 7757-7761


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.