Thermodynamics of the hydration shell. 2. Excess volume and compressibility of a hydrophobic solute

Journal of Physical Chemistry

Volumn 100, Issue 7, 1996, Pages 2681-2688

  Matubayasi, Nobuyuki ^a   Levy, Ronald M ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33748658848     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp951618b     Document Type: Article

References (29)

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19. The experimental value reported in ref 18 is not the excess isothermal compressibility but the excess adiabatic compressibility. The excess isothermal compressibility can be calculated from the excess adiabatic compressibility, the excess expansion coefficient, and the excess heat capacity through a thermodynamic identity and is found to still be negative.
20. 17,18 The temperature dependence of Δκ is a third-order derivative of the chemical potential. A better framework for understanding such a higher order property is clearly needed.
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