-
9
-
-
0000306467
-
-
(a) Nosaka, Y.; Yamaguchi, K.; Miyama, H.; Hayashi, H. Chem. Lett. 1988, 605.
-
(1988)
Chem. Lett.
, pp. 605
-
-
Nosaka, Y.1
Yamaguchi, K.2
Miyama, H.3
Hayashi, H.4
-
10
-
-
10644227368
-
-
(b) Nosaka, Y.; Ohta, N.; Fukuyama, T. Fujii, N. J. Colloid Interface Sci. 1993, 115, 23.
-
(1993)
J. Colloid Interface Sci.
, vol.115
, pp. 23
-
-
Nosaka, Y.1
Ohta, N.2
Fukuyama, T.3
Fujii, N.4
-
11
-
-
0024012224
-
-
(a) Steigerwald, M. L.; Alivisatos, A. P.; Gibson, J. M.; Harris, T. .D.; Kortan, A. R.; Muller, A. J.; Thayer, A. M.; Duncan, T. M.; Douglass, D. C.; Brus, L. E. J. Am. Chem. Soc. 1988, 110, 3046.
-
(1988)
J. Am. Chem. Soc.
, vol.110
, pp. 3046
-
-
Steigerwald, M.L.1
Alivisatos, A.P.2
Gibson, J.M.3
Harris, T.D.4
Kortan, A.R.5
Muller, A.J.6
Thayer, A.M.7
Duncan, T.M.8
Douglass, D.C.9
Brus, L.E.10
-
12
-
-
1842600367
-
-
(b) Kortan, A. R.; Hull, R.; Opila, R. L.; Bawendi, M. G.; Steigerwald, M. L.; Alivisatos, A. P.; Carrol, P. J.; Brus, L. E. J. Am. Chem. Soc. 1990, 112, 1327.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 1327
-
-
Kortan, A.R.1
Hull, R.2
Opila, R.L.3
Bawendi, M.G.4
Steigerwald, M.L.5
Alivisatos, A.P.6
Carrol, P.J.7
Brus, L.E.8
-
13
-
-
0024681309
-
-
(a) Hayes, D.; Mićić, O. I.; Nenadović, M. T.; Swayambunathan, V.; Meisel, D. J. Phys. Chem. 1989, 93, 4603.
-
(1989)
J. Phys. Chem.
, vol.93
, pp. 4603
-
-
Hayes, D.1
Mićić, O.I.2
Nenadović, M.T.3
Swayambunathan, V.4
Meisel, D.5
-
14
-
-
0000759558
-
-
(b) Swayambunathan, V.; Hayes, D.; Schmidt, K. H.; Liao, Y. X.; Meisel, D. J. Am. Chem. Soc. 1990, 112, 3831.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 3831
-
-
Swayambunathan, V.1
Hayes, D.2
Schmidt, K.H.3
Liao, Y.X.4
Meisel, D.5
-
16
-
-
0001158537
-
-
Herron, N.; Wang, Y.; Eckert, H. J. Am. Chem. Soc. 1990, 112, 1322.
-
(1990)
J. Am. Chem. Soc.
, vol.112
, pp. 1322
-
-
Herron, N.1
Wang, Y.2
Eckert, H.3
-
17
-
-
0013607325
-
-
(a) Yanagida, S.; Enokida, T.; Shindo, A.; Shiragami, T.; Ogata, T.; Fukumi, T.; Sakaguchi, T.; Mori, H.; Sakata, T. Chem. Lett. 1990, 1773.
-
(1990)
Chem. Lett.
, pp. 1773
-
-
Yanagida, S.1
Enokida, T.2
Shindo, A.3
Shiragami, T.4
Ogata, T.5
Fukumi, T.6
Sakaguchi, T.7
Mori, H.8
Sakata, T.9
-
18
-
-
0343417396
-
-
(b) Ogata, T.; Hosokawa, H.; Oshiro, T.; Wada, Y.; Sakata, T.; Mori, H.; Yanagida, S. Chem. Lett. 1992, 1665.
-
(1992)
Chem. Lett.
, pp. 1665
-
-
Ogata, T.1
Hosokawa, H.2
Oshiro, T.3
Wada, Y.4
Sakata, T.5
Mori, H.6
Yanagida, S.7
-
19
-
-
0001738799
-
-
(c) Yanagida, S.; Ogata, T.; Shindo, A.; Hosokawa, H.; Mori, H.; Sakata, T.; Wada, Y. Bull. Chem. Soc. Jpn. 1995, 68, 752.
-
(1995)
Bull. Chem. Soc. Jpn.
, vol.68
, pp. 752
-
-
Yanagida, S.1
Ogata, T.2
Shindo, A.3
Hosokawa, H.4
Mori, H.5
Sakata, T.6
Wada, Y.7
-
20
-
-
0026924430
-
-
(a) Resch, U.; Eychmüller, A.; Haase, M.; Weller, H. Langmuir 1992, 8, 2215.
-
(1992)
Langmuir
, vol.8
, pp. 2215
-
-
Resch, U.1
Eychmüller, A.2
Haase, M.3
Weller, H.4
-
21
-
-
0040999420
-
-
(b) Vossmeyer, T.; Katsikas, L.; Giersig, M.; Popovic, I. G.; Diesner, K.; Chemseddine, A.; Eychmüller, A.; Weller, H. J. Phys. Chem. 1994, 98, 7665.
-
(1994)
J. Phys. Chem.
, vol.98
, pp. 7665
-
-
Vossmeyer, T.1
Katsikas, L.2
Giersig, M.3
Popovic, I.G.4
Diesner, K.5
Chemseddine, A.6
Eychmüller, A.7
Weller, H.8
-
22
-
-
0000693008
-
-
Colvin, V. L.; Goldstein, A. N.; Alivisatos, A. P. J. Am. Chem. Soc. 1992, 114, 5221.
-
(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 5221
-
-
Colvin, V.L.1
Goldstein, A.N.2
Alivisatos, A.P.3
-
23
-
-
0002935761
-
-
Mahamuni, S.; Khosravi, A. A.; Kundu, M.; Kshirsagar, A.; Bedekar, A.; Avasare, D. B.; Singh, P.; Kulkarni, S. K. J. Appl. Phys. 1993, 73, 5237.
-
(1993)
J. Appl. Phys.
, vol.73
, pp. 5237
-
-
Mahamuni, S.1
Khosravi, A.A.2
Kundu, M.3
Kshirsagar, A.4
Bedekar, A.5
Avasare, D.B.6
Singh, P.7
Kulkarni, S.K.8
-
24
-
-
0013546112
-
-
(a) Torimoto, T.; Uchida, H.; Sakata, T.; Mori, H.; Yoneyama, H. J. Am. Chem. Soc. 1993, 115, 1874.
-
(1993)
J. Am. Chem. Soc.
, vol.115
, pp. 1874
-
-
Torimoto, T.1
Uchida, H.2
Sakata, T.3
Mori, H.4
Yoneyama, H.5
-
25
-
-
0343351095
-
-
(b) Torimoto, T.; Sakata, T.; Mori, H.; Yoneyama, H. J. Phys. Chem. 1994, 98, 3036.
-
(1994)
J. Phys. Chem.
, vol.98
, pp. 3036
-
-
Torimoto, T.1
Sakata, T.2
Mori, H.3
Yoneyama, H.4
-
26
-
-
0001201552
-
-
(c) Torimoto, T.; Maeda, K.; Sakata, T.; Mori, H.; Yoneyama, H. J. Phys. Chem. 1994, 98, 13658.
-
(1994)
J. Phys. Chem.
, vol.98
, pp. 13658
-
-
Torimoto, T.1
Maeda, K.2
Sakata, T.3
Mori, H.4
Yoneyama, H.5
-
27
-
-
0028746445
-
-
(d) Inoue, H.; Ichiroku, N.; Torimoto, T.; Sakata, T.; Mori, H.; Yoneyama, H. Langmuir 1994, 10, 4517.
-
(1994)
Langmuir
, vol.10
, pp. 4517
-
-
Inoue, H.1
Ichiroku, N.2
Torimoto, T.3
Sakata, T.4
Mori, H.5
Yoneyama, H.6
-
28
-
-
0000939999
-
-
Murray, C. B.; Norris, D. J.; Bawendi, M. G. J. Am. Chem. Soc. 1993, 115, 8706.
-
(1993)
J. Am. Chem. Soc.
, vol.115
, pp. 8706
-
-
Murray, C.B.1
Norris, D.J.2
Bawendi, M.G.3
-
29
-
-
33751386497
-
-
Rajh, T.; Mićić, O. I.; Nozik, A. J. J. Phys. Chem. 1993, 97, 11999.
-
(1993)
J. Phys. Chem.
, vol.97
, pp. 11999
-
-
Rajh, T.1
Mićić, O.I.2
Nozik, A.J.3
-
30
-
-
0347303427
-
-
(a) Dannhauser, T.; O'Neil, M.; Johansson, K.; Whitten, D.; McLendon, G. J. Phys. Chem. 1986, 90, 6074.
-
(1986)
J. Phys. Chem.
, vol.90
, pp. 6074
-
-
Dannhauser, T.1
O'Neil, M.2
Johansson, K.3
Whitten, D.4
McLendon, G.5
-
31
-
-
33751554855
-
-
(b) O'Neil, M.; Marohn, J.; McLendon, G. J. Phys. Chem. 1990, 94, 4356.
-
(1990)
J. Phys. Chem.
, vol.94
, pp. 4356
-
-
O'Neil, M.1
Marohn, J.2
McLendon, G.3
-
32
-
-
0011470141
-
-
Wang, Y.; Suna, A.; McHugh, J.; Hilinski, E. F.; Lucas, P. A. Johnson, R. D. J. Chem. Phys. 1990, 92, 6927.
-
(1990)
J. Chem. Phys.
, vol.92
, pp. 6927
-
-
Wang, Y.1
Suna, A.2
McHugh, J.3
Hilinski, E.F.4
Lucas, P.A.5
Johnson, R.D.6
-
34
-
-
0000245979
-
-
(b) Chandler, R. R.; Coffer, J. L.; Atherton, S. J.; Snowden, P. T. J. Phys. Chem. 1992, 96, 2713.
-
(1992)
J. Phys. Chem.
, vol.96
, pp. 2713
-
-
Chandler, R.R.1
Coffer, J.L.2
Atherton, S.J.3
Snowden, P.T.4
-
36
-
-
0000285210
-
-
(d) Coffer, J. L.; Chandler, R. R.; Gutsche, C. D.; Alam, I.; Pinizzotto, R. F.; Yang, H. J. Phys. Chem. 1993, 97, 696.
-
(1993)
J. Phys. Chem.
, vol.97
, pp. 696
-
-
Coffer, J.L.1
Chandler, R.R.2
Gutsche, C.D.3
Alam, I.4
Pinizzotto, R.F.5
Yang, H.6
-
38
-
-
0025751440
-
-
Eychmüller, A.; Hässelbarth, A.; Katsikas, L.; Weller, H. Ber. Bunsenges. Phys. Chem. 1991, 95, 79.
-
(1991)
Ber. Bunsenges. Phys. Chem.
, vol.95
, pp. 79
-
-
Eychmüller, A.1
Hässelbarth, A.2
Katsikas, L.3
Weller, H.4
-
39
-
-
19944419506
-
-
Bawendi, M. G.; Carroll, P. J.; Wilson, W. L.; Brus, L. E. J. Chem. Phys. 1992, 96, 946.
-
(1992)
J. Chem. Phys.
, vol.96
, pp. 946
-
-
Bawendi, M.G.1
Carroll, P.J.2
Wilson, W.L.3
Brus, L.E.4
-
41
-
-
33751158375
-
-
Zhang, J. Z.; O'Neil, R. H.; Roberti, T. W. J. Phys. Chem. 1994, 98, 3859.
-
(1994)
J. Phys. Chem.
, vol.98
, pp. 3859
-
-
Zhang, J.Z.1
O'Neil, R.H.2
Roberti, T.W.3
-
42
-
-
0001657224
-
-
Nirmal, M.; Murray, C. B.; Bawendi, M. G. Phys. Rev. B 1994, 50, 2293.
-
(1994)
Phys. Rev. B
, vol.50
, pp. 2293
-
-
Nirmal, M.1
Murray, C.B.2
Bawendi, M.G.3
-
45
-
-
0000002615
-
-
Nosaka, Y.; Yamaguchi, K.; Kuwabara, A.; Miyama, H.; Baba, R.; Fujishima, A. J. Photochem. Photobiol. A: Chem. 1992, 64, 375.
-
(1992)
J. Photochem. Photobiol. A: Chem.
, vol.64
, pp. 375
-
-
Nosaka, Y.1
Yamaguchi, K.2
Kuwabara, A.3
Miyama, H.4
Baba, R.5
Fujishima, A.6
-
46
-
-
0000574340
-
-
Willner, I.; Eichen, Y.; Frank, A. J.; Fox, M. A. J. Phys. Chem. 1993, 97, 7264.
-
(1993)
J. Phys. Chem.
, vol.97
, pp. 7264
-
-
Willner, I.1
Eichen, Y.2
Frank, A.J.3
Fox, M.A.4
-
48
-
-
37049112150
-
-
(b) Yanagida, S.; Azuma, T.; Midori, Y.; Pac, C.; Sakurai, H. J. Chem. Soc., Perkin Trans. 2 1985, 1487.
-
(1985)
J. Chem. Soc., Perkin Trans. 2
, pp. 1487
-
-
Yanagida, S.1
Azuma, T.2
Midori, Y.3
Pac, C.4
Sakurai, H.5
-
49
-
-
0001260879
-
-
Kanemoto, M.; Shiragami, T.; Pac. C.; Yanagida, S. J. Phys. Chem. 1992, 96, 3521.
-
(1992)
J. Phys. Chem.
, vol.96
, pp. 3521
-
-
Kanemoto, M.1
Shiragami, T.2
Pac, C.3
Yanagida, S.4
-
50
-
-
0001123738
-
-
(a) Kanemoto, M.; Ishihara, K.; Wada, Y.; Sakata, T.; Mori, H.; Yanagida, S. Chem. Lett. 1992, 835.
-
(1992)
Chem. Lett.
, pp. 835
-
-
Kanemoto, M.1
Ishihara, K.2
Wada, Y.3
Sakata, T.4
Mori, H.5
Yanagida, S.6
-
51
-
-
0043278755
-
-
(b) Kanemoto, M.; Ankyu, H.; Wada, Y.; Yanagida, S. Chem. Lett. 1992, 2113.
-
(1992)
Chem. Lett.
, pp. 2113
-
-
Kanemoto, M.1
Ankyu, H.2
Wada, Y.3
Yanagida, S.4
-
52
-
-
0001190863
-
-
(c) Kanemoto, M.; Nomura, M.; Wada, Y.; Yanagida, S. Chem. Lett. 1993, 1687.
-
(1993)
Chem. Lett.
, pp. 1687
-
-
Kanemoto, M.1
Nomura, M.2
Wada, Y.3
Yanagida, S.4
-
53
-
-
0024622631
-
-
(a) Yanagida, S.; Ishimaru, Y.; Miyake, Y.; Shiragami, T.; Pac, C.; Hashimoto, K.; Sakata, T.; J. Phys. Chem. 1989, 93, 2576.
-
(1989)
J. Phys. Chem.
, vol.93
, pp. 2576
-
-
Yanagida, S.1
Ishimaru, Y.2
Miyake, Y.3
Shiragami, T.4
Pac, C.5
Hashimoto, K.6
Sakata, T.7
-
54
-
-
0001612620
-
-
(b) Yanagida, S.; Yoshiya, M.; Shiragami, T.; Pac, C.; Mori, H.; Fujita, H. J. Phys. Chem. 1990, 94, 3104.
-
(1990)
J. Phys. Chem.
, vol.94
, pp. 3104
-
-
Yanagida, S.1
Yoshiya, M.2
Shiragami, T.3
Pac, C.4
Mori, H.5
Fujita, H.6
-
55
-
-
0000268289
-
-
(c) Shiragami, T.; Ankyu, H.; Fukami, S.; Pac. C.; Yanagida, S.; Mori, H.; Fujita, H. J. Chem. Soc., Faraday Trans. 1992, 88, 1055.
-
(1992)
J. Chem. Soc., Faraday Trans.
, vol.88
, pp. 1055
-
-
Shiragami, T.1
Ankyu, H.2
Fukami, S.3
Pac, C.4
Yanagida, S.5
Mori, H.6
Fujita, H.7
-
56
-
-
0001644460
-
-
(d) Shiragami, T.; Fukami, S.; Pac, C.; Yanagida, S. J. Chem. Soc., Faraday Trans. 1993, 89, 1857.
-
(1993)
J. Chem. Soc., Faraday Trans.
, vol.89
, pp. 1857
-
-
Shiragami, T.1
Fukami, S.2
Pac, C.3
Yanagida, S.4
-
57
-
-
0000394647
-
-
(e) Shiragami, T.; Fukami, S.; Wada, Y.; Yanagida, S. J. Phys. Chem. 1993, 97, 12882.
-
(1993)
J. Phys. Chem.
, vol.97
, pp. 12882
-
-
Shiragami, T.1
Fukami, S.2
Wada, Y.3
Yanagida, S.4
-
58
-
-
33845373658
-
-
(a) Yanagida, S.; Mizumoto, K.; Pac, C. J. Am. Chem. Soc. 1986, 98, 647.
-
(1986)
J. Am. Chem. Soc.
, vol.98
, pp. 647
-
-
Yanagida, S.1
Mizumoto, K.2
Pac, C.3
-
59
-
-
0000716604
-
-
(b) Shiragami, T.; Fukami, S.; Pac. C.; Wada, Y.; Yanagida, S. Bull Chem. Soc. Jpn. 1993, 66, 2461.
-
(1993)
Bull Chem. Soc. Jpn.
, vol.66
, pp. 2461
-
-
Shiragami, T.1
Fukami, S.2
Pac, C.3
Wada, Y.4
Yanagida, S.5
-
61
-
-
0003673335
-
-
Koningsberger, D. C., Prins, R., Eds. Wiley: New York
-
Koningsberger, D. C., Prins, R., Eds. X-ray Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS. and XANES; Wiley: New York, 1988.
-
(1988)
X-ray Absorption: Principles, Applications, Techniques of EXAFS, SEXAFS. and XANES
-
-
-
62
-
-
0021400304
-
-
Sinfelt, J. H.; Via, G. H.; Lytle, F. W. Catal. Rev.-Sci. Eng. 1984, 26, 81.
-
(1984)
Catal. Rev.-Sci. Eng.
, vol.26
, pp. 81
-
-
Sinfelt, J.H.1
Via, G.H.2
Lytle, F.W.3
-
66
-
-
0024302379
-
-
(a) Herron, N.; Wang, Y.; Eddy, M. M.; Stucky, G. D.; Cox, D. E.; Moller, K.; Bein, T. J. Am. Chem. Soc. 1989, 111, 530.
-
(1989)
J. Am. Chem. Soc.
, vol.111
, pp. 530
-
-
Herron, N.1
Wang, Y.2
Eddy, M.M.3
Stucky, G.D.4
Cox, D.E.5
Moller, K.6
Bein, T.7
-
67
-
-
0024629505
-
-
(b) Moller, K.; Eddy, M. M.; Stucky, G. D.; Herron, N.; Bein, T. J. Am. Chem. Soc. 1989, 111, 2564.
-
(1989)
J. Am. Chem. Soc.
, vol.111
, pp. 2564
-
-
Moller, K.1
Eddy, M.M.2
Stucky, G.D.3
Herron, N.4
Bein, T.5
-
68
-
-
0000180012
-
-
(a) Marcus, M. A.; Flood, W.; Steigerwald, M.; Brus, L. Bawendi, M. J. Phys. Chem. 1991, 95, 1572.
-
(1991)
J. Phys. Chem.
, vol.95
, pp. 1572
-
-
Marcus, M.A.1
Flood, W.2
Steigerwald, M.3
Brus, L.4
Bawendi, M.5
-
69
-
-
0001059213
-
-
(b) Marcus, M. A.; Brus, L. E.; Murray, C.; Bawendi, M. G.; Prasad, A.; Alivisatos, A. P. NanoSTRUCTURED MATERIALS 1992, 1, 323.
-
(1992)
NanoSTRUCTURED MATERIALS
, vol.1
, pp. 323
-
-
Marcus, M.A.1
Brus, L.E.2
Murray, C.3
Bawendi, M.G.4
Prasad, A.5
Alivisatos, A.P.6
-
72
-
-
85088620158
-
-
note
-
2+ in CdS-DMF solution can be negligible for our experiments.
-
-
-
-
75
-
-
11544359487
-
-
Majetich, S. A.; Carter, A. C.; Belot, J.; McCullough, R. D. J. Phys Chem. 1994, 98, 13705.
-
(1994)
J. Phys Chem.
, vol.98
, pp. 13705
-
-
Majetich, S.A.1
Carter, A.C.2
Belot, J.3
McCullough, R.D.4
-
77
-
-
0027677677
-
-
Sakane, H.; Miyanaga, T.; Watanabe, I.; Matsubayashi, N.; Ikeda, S.; Yokoyama, Y. Jpn. J. Appl Phys. 1993, 32, 4641.
-
(1993)
Jpn. J. Appl Phys.
, vol.32
, pp. 4641
-
-
Sakane, H.1
Miyanaga, T.2
Watanabe, I.3
Matsubayashi, N.4
Ikeda, S.5
Yokoyama, Y.6
-
78
-
-
0006763630
-
-
McKale, A. G.; Veal, B. W.; Paulicas, A. P.; Chan, S. K.; Knapp, G. J. Am. Chem. Soc. 1988, 110, 3763.
-
(1988)
J. Am. Chem. Soc.
, vol.110
, pp. 3763
-
-
McKale, A.G.1
Veal, B.W.2
Paulicas, A.P.3
Chan, S.K.4
Knapp, G.5
-
79
-
-
0001197071
-
-
Lytle, F. W.; Sayers, D. E.; Stern, E. A. Phys. B 1989, 158, 701.
-
(1989)
Phys. B
, vol.158
, pp. 701
-
-
Lytle, F.W.1
Sayers, D.E.2
Stern, E.A.3
-
82
-
-
0011182247
-
-
Ozutsumi, K.; Takamuku, T.; Ishiguro, S.; Ohtaki, H. Bull. Chem. Soc. Jpn. 1989, 62, 1875.
-
(1989)
Bull. Chem. Soc. Jpn.
, vol.62
, pp. 1875
-
-
Ozutsumi, K.1
Takamuku, T.2
Ishiguro, S.3
Ohtaki, H.4
-
83
-
-
0001173075
-
-
Ozutsumi, K.; Koide, M.; Suzuki, H.; Ishiguro, S. J. Phys. Chem. 1993, 97, 500.
-
(1993)
J. Phys. Chem.
, vol.97
, pp. 500
-
-
Ozutsumi, K.1
Koide, M.2
Suzuki, H.3
Ishiguro, S.4
-
85
-
-
37049081322
-
-
Dance, I. G.; Garbutt, R. G.; Craig, D. C.; Scudder, M. L.; Bailey, T. D. J. Chem. Soc., Chem. Commun. 1987, 1164.
-
(1987)
J. Chem. Soc., Chem. Commun.
, pp. 1164
-
-
Dance, I.G.1
Garbutt, R.G.2
Craig, D.C.3
Scudder, M.L.4
Bailey, T.D.5
-
86
-
-
0001029561
-
-
Dance, I. G.; Garbutt, R. G.; Scudder, M. L. Inorg. Chem. 1990, 29, 1571.
-
(1990)
Inorg. Chem.
, vol.29
, pp. 1571
-
-
Dance, I.G.1
Garbutt, R.G.2
Scudder, M.L.3
-
87
-
-
0542429633
-
-
Herrno, N.; Calabrese, J. C.; Farneth, W. E.; Wang, Y. Science 1993, 259, 1426.
-
(1993)
Science
, vol.259
, pp. 1426
-
-
Herrno, N.1
Calabrese, J.C.2
Farneth, W.E.3
Wang, Y.4
-
89
-
-
84985609327
-
-
(b) Craig, D.; Dance, I. G.; Garbutt, R. Angew. Chem., Int. Ed. Engl. 1986, 25, 165.
-
(1986)
Angew. Chem., Int. Ed. Engl.
, vol.25
, pp. 165
-
-
Craig, D.1
Dance, I.G.2
Garbutt, R.3
-
91
-
-
33748633019
-
-
note
-
The terrace model consists of 457 interior cadmium atoms and 266 surface cadmium atoms. Each interior cadmium atom coordinates to four sulfur atoms in a hexagonal crystal structure. In the present model, the total coordination number of each cadmium atom is assumed to be four, even at the surface. On the surface of the terrace models, there are 36 cadmium atoms on a corner, which are each assumed to coordinate to one sulfur atom and three DMF oxygen atoms, 96 edge cadmium atoms, which each coordinate to two sulfur atoms and two DMF oxygens, 86 terrace cadmium atoms, which each coordinate to three sulfur atoms and one DMF oxygen, and 48 kink cadmium atoms, which each coordinate to four sulfur atoms. Thus, the coordination numbers of the Cd-S and Cd-O shells are calculated to be 3.5 [(4 × 457 + 1 × 36 + 2 × 96 + 3 × 86 + 4 × 48)/723] and 0.5 [4-3.5], respectively. For the step model, the coordination numbers of the Cd-S and Cd-O shells can be similarly calculated as 3.0 [(4 × 133 + 1 × 72 + 2 × 36 + 3 × 38 + 4 × 48)/327] and 1.0 [4-3.0], respectively.
-
-
-
-
92
-
-
0001112241
-
-
Ramsden, J. J.; Grätzel, M. J. Chem. Soc., Faraday Trans. 1 1984, 80, 919.
-
(1984)
J. Chem. Soc., Faraday Trans. 1
, vol.80
, pp. 919
-
-
Ramsden, J.J.1
Grätzel, M.2
|