Chemical repercussions of orbital interactions through bond and through space The reactivity of the double bond in unsaturated cyclic sulphones towards aziridine formation and epoxidation

Tetrahedron

Volumn 40, Issue 13, 1984, Pages 2487-2503

  Alan Aitken, R ^a   Gosney, Ian ^a   Farries, Hugh ^a   Palmer, Michael H ^a   Simpson, Isobel ^a   Cadogan, John I G ^b   Tinley, Edward J ^b  

^a UNIVERSITY OF EDINBURGH   (United Kingdom)

^b BP EXPLORATION   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33748591453     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(01)83501-8     Document Type: Article

References (77)

1. Generation of carbethoxynitrene by .alpha. elimination and its reactions with olefins under two-phase conditions
2. Electronic state of ethoxycarbonylnitrene generated by .ALPHA.-elimination under two-phase conditions.
3. Studies concerning azabicyclobutanes
4. Untersuchungen in der Cyclobutanreihe, XI. Über die stereoisomeren Cyclooctatetraen-dichloride und dascis-3.4-Dichlor-cyclobuten
5. Reactions of nitrenes with strained olefins. Nitrene additions to the bicyclo[2.2.1]hept-2-ene system
6. Effect of substituents on the reactivity of a double bond towards [?4 s +?2 s ] and epoxidation reactions : a chemical manifestation of orbital interactions through space
7. Orbital Reactions Through Space. Part III. Rate Enhancement in Epoxidation of an Olefin by a Proximate Hydroxyl Group
8. Orbital interactions. XI. Application of photoelectron spectroscopy to the study of orbital interactions in some 2- and 9-substituted octahydrodimethanonaphthalenes
9. Orbital interactions. VIII. Competition kinetic measurements of the Birch reduction of some compounds having the bicyclo[2,2,1]heptadiene framework as a means of investigating orbital interactions through space in these systems
10. Orbital interactions. IX. The effect of remote substituents on the electrophilic nitration of a series of 11-substitutedexo-hexahydro-7,10-methanofluoranthenes
11. Orbital interactions. X. The effect of remote substituents on the electrophilic bromination of a series of stereoisomeric 9-substitutedhexahydro-l,4-methanobiphenylenes
12. Effects of Through-Bond Interaction
13. Sequence of Orbitals in Sulfones and Sulfodiimides
14. Photoelektronenspektren und Moleküleigenschaften, XLV. Schwefelsäure-Derivate: Alkyl-, Vinyl- und Arylsulfone, Alkylsulfoimide und Sulfurylhalogenide
15. Theory and application of photoelectron spectroscopy. 31. Through-conjugation through the sulfone group in 2,5-di-tert-butylthiophene 1,1-dioxide
16. Non-empirical calculations of the nature of the bonding in thiophen, thiophen S-oxide, and thiophen SS-dioxide
17. The direct CI method
18. Microwave Spectrum, Structure, and Dipole Moment of Cyclohexene
19. Photoelektron-Spektren von Cycloalkenen und Cycloalkadienen. Vorl�ufige Mitteilung
20. Photoelektronspektroskopische Bestimmung der Wechselwirkung zwischen nicht-konjugierten Doppelbindungen [1]. Vorl�ufige Mitteilung
21. The Decomposition of Ethyl Azidoformate in Cyclohexene and in Cyclohexane1
22. Über das abgestufte Additionsvermögen von ungesättigten Ringsystemen
23. Über den sterischen Verlauf von Additions- und Substitutions-reaktionen. IV. Die Phenyl-azid-reaktion in der Fenchen-reihe
24. Über den sterischen Verlauf von Additions- und Substitutions-reaktionen. V. Der sterische Verlauf der Phenylazid-reaktion
25. 1,3-Dipolar Cycloadditions. Past and Future
26. Zur Kenntnis der Dien-Synthese, X. Mitteil.: Über die Dien-Synthese mit α,β-ungesättigten Nitrokörpern, Sulfonen und Thio-Äthern
27. Zur Polymerisation cyclischer Kohlenwasserstoffe. I. Mitteilung: Die polymeren Formen des Cyclopentadiens
28. Molybdenum-catalysed epoxidation of olefins with alkyl hydroperoxides I. Kinetic and product studies