A heterodimetallic platinum-cobalt carboxylate complex PtIV Co2II (μ, η2 - OOCCMe3)4 (OOCCMe3)2 (OH)2 (HOOCCMe3)4: Synthesis and structure

Inorganic Chemistry Communications

Volumn 9, Issue 10, 2006, Pages 1026-1028

  Nefedov, Sergei E ^a   Kozitsyna, Natalia Yu ^a   Cherkashina, Natalia V ^a   Fukin, Georgy K ^b   Vargaftik, Michael N ^a   Moiseev, Ilya I ^a  

^a KURNAKOV INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Russian Federation)

^b G A RAZUVAEV INSTITUTE OF ORGANOMETALLIC CHEMISTRY   (Russian Federation)

Author keywords

Cobalt; Heterodimetallic complex; Pivalate bridging complex; Platinum; X ray structure

Indexed keywords

EID: 33748588408     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2006.05.012     Document Type: Article

References (24)

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16. t fragments are disordered over two positions C(3)-C(5) and C(3′)-C(5′) with occupancies approximately 0.7 and 0.3; atoms C(13)-C(15) and C(13′)-C(15′) with occupancies approximately 0.6 and 0.4; atoms C(18)-C(20) and C(18′)- C(20′) with occupancies approximately 0.4 and 0.6; atoms C(23), C(24) and C(23′), C(24′) with occupancies approximately 0.7 and 0.3, respectively. All calculations were performed with the use of the SAINT [14] and SHELXTL-97 [15] program packages.
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