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Volumn 100, Issue 8, 1996, Pages 3030-3036

Electron-transfer reactions with significant inner reorganization energies. Two-electron oxidation of derivatives of 1,4-bis(dialkylamino)-1,3-butadiene

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EID: 33748527559     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp951909k     Document Type: Article
Times cited : (47)

References (51)
  • 3
    • 0006200007 scopus 로고
    • Liebman, J. F., Greenberg, A., Eds.; VCH Publishers: Deerfield Beach, FL, Chapter 1
    • (b) Nelsen, S. F. In Molecular Structures and Energetics; Liebman, J. F., Greenberg, A., Eds.; VCH Publishers: Deerfield Beach, FL, 1986; Vol. 3, Chapter 1, pp 1-86.
    • (1986) Molecular Structures and Energetics , vol.3 , pp. 1-86
    • Nelsen, S.F.1
  • 32
    • 85033040275 scopus 로고    scopus 로고
    • note
    • (a) For a one-electron reaction, the value for the separation of peak potentials approaches a limit of 2.219RT/F (57.0 mV at 298 K) as the standard electron-transfer rate constant increases (reversibility) and the distance between the switching potential and reversible formal potential increases. This fact can be deduced from the data presented in Tables 1 and 2 of ref 8b. For switching potentials 100 and 200 mV removed from the reversible potential, the values at 298 K are 64 and 60 mV, respectively.
  • 34
    • 85033054952 scopus 로고    scopus 로고
    • note
    • (a) For comparison, experimental activation enthalpies for heterogeneous electron-transfer reactions of species with small inner reorganization energies typically fall in the range 5-7 kcal/mol. See ref 9b for benzophenone and ref 9c for nitromesitylene.
  • 40
    • 85033037388 scopus 로고    scopus 로고
    • note
    • 10e
  • 42
    • 85033036719 scopus 로고    scopus 로고
    • Manuscript in preparation
    • Evans, D. H. Manuscript in preparation.
    • Evans, D.H.1
  • 46
    • 85033052216 scopus 로고    scopus 로고
    • note
    • 14b
  • 49
    • 85033041269 scopus 로고    scopus 로고
    • note
    • 16b
  • 50
    • 0000820968 scopus 로고
    • Bard, A. J., Ed.; Marcel Dekker: New York
    • (b) Evans, D. H.; O'Connell, K. M. In Electroanalytical Chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1986; Vol. 14, pp 113-207.
    • (1986) Electroanalytical Chemistry , vol.14 , pp. 113-207
    • Evans, D.H.1    O'Connell, K.M.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.