High-performance liquid chromatography analysis of rubber allergens in protective gloves used in health care

Contact Dermatitis

Volumn 55, Issue 4, 2006, Pages 210-215

  Bergendorff, Ola ^a   Persson, C ^a   Hansson, C ^a  

^a LUND UNIVERSITY   (Sweden)

Author keywords

Allergic contact dermatitis; High performance liquid chromatography; Medical gloves; Mercaptobenzothiazoles; Rubber; Thiurams; Zinc dithiocarbamates

Indexed keywords

2 MERCAPTOBENZOTHIAZOLE; ACETONE; ALLERGEN; CARBAMIC ACID DERIVATIVE; DIBUTYLDITHIOCARBAMATE ZINC; DISULFIRAM; RUBBER; UNCLASSIFIED DRUG; ZINC DITHIOCARBAMATE DERIVATIVE; ZINC PENTAMETHYLENEDITHIOCARBAMATE;

ARTICLE; CHEMICAL ANALYSIS; EXTRACTION; HEALTH CARE; HEALTH SURVEY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PROTECTIVE CLOTHING; ROOM TEMPERATURE; SWEDEN; VALIDATION STUDY;

ALLERGENS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; DERMATITIS, OCCUPATIONAL; GLOVES, PROTECTIVE; HAND DERMATOSES; HEALTH PERSONNEL; HUMANS; LATEX HYPERSENSITIVITY; PREDICTIVE VALUE OF TESTS; RUBBER; THIOCARBAMATES;

EID: 33748474207     PISSN: 01051873     EISSN: 16000536     Source Type: Journal    
DOI: 10.1111/j.1600-0536.2006.00912.x     Document Type: Article

References (12)

1. Geier J, Lessmann H, Uter W, Schnuch A. Occupational rubber glove allergy: results of the Information Network of Departments of Dermatology (IVDK), 1995-2001. Contact Dermatitis 2003: 48: 39-44.
2. Hansson C, Agrup G. Stability of the mercaptobenzothiazole compounds. Contact Dermatitis 1993: 28: 29-34.
3. Bergendorff O, Hansson C. The spontaneous formation of thiuram disulfides in solutions of iron (III) dithiocarbamates. J Agric Food Chem 2002: 50: 1092-1096.
4. Mathieu C, Herbreteau B, Lafosse M, Morin P, Renaud M, Cardinet C, Dreux M. Liquid chromatography of unstable zinc dithiocarbamates. Application to rubber gloves analysis. J High Resolut Chromatogr 2000: 23: 565-566.
5. Bergendorff O, Persson C, Hansson C. HPLC analysis of alkyl thioureas in an orthopaedic brace and patch testing with pure ethylbutylthiourea. Contact Dermatitis 2004: 51: 273-277.
6. Bergendorff O, Persson C, Hansson C. Extraction of haptens from solid products and their delivery to the skin, exemplified by dithiocarbamates from rubber gloves. Contact Dermatitis 2005: 53: 22-26.
7. Knudsen B B, Larsen E, Egsgaard H, Menne T. Release of thiurams and carbamates from rubber gloves. Contact Dermatitis 1993: 28: 63-69.
8. Knudsen B B, Hametner C, Seycek O, Koch H-U, Peters K-P. Allergologically relevant rubber accelerators in single-use medical gloves. Contact Dermatitis 2000: 43: 9-15.
9. Kaniwa M, Isama K, Nakamura A et al. Identification of causative chemicals of allergic contact dermatitis using a combination of patch testing in patients and chemical analysis. Application to cases from rubber gloves. Contact Dermatitis 1994: 31: 65-71.
10. Depree G J, Bledsoe T A, Siegel P D. Determination of zinc dialkyldithiocarbamates in latex condoms. J Chromatogr Sci 2004: 42: 80-84.
11. Brehler R, Rütter A, Kütting B. Allergenicity of natural rubber latex gloves. Contact Dermatitis 2002: 46: 65-71.
12. Nieuwenhuizen P J, Reedijk J, Van Duin M, McGill W J. Thiuram- and dithiocarbamate-accelerated sulfur vulcanization from the chemist's perspective: methods, materials and mechanisms reviewed. Rubber Chem Technol 1997: 70: 368-429