Kinetic modelling of homogeneous low temperature multi-pollutant oxidation by ozone: The importance of SO and HCl in predicting oxidation

Journal of Zhejiang University: Science

Volumn 7, Issue SUPPL. 2, 2006, Pages 335-339

  Wei, Lin Sheng ^a   Zhou, Jun Hu ^a   Wang, Zhi Hua ^a   Cen, Ke Fa ^a  

^a ZHEJIANG UNIVERSITY   (China)

Author keywords

Kinetic modelling; Low temperature oxidation; Multi pollutant removal; Reaction mechanism

Indexed keywords

CHLORINATION; CHLORINE COMPOUNDS; FLUE GASES; NITROGEN OXIDES; OXYGEN; OZONE; REMOVAL; SULFUR DIOXIDE; TEMPERATURE;

CHLORINE-CONTAINING COMPOUNDS; HCL; HG REACTIONS; KINETIC MODELLING; LOW TEMPERATURE OXIDATION; MULTI POLLUTANT REMOVAL; OXYGEN CONTAINING COMPOUNDS; REACTION MECHANISM; SO;

OXIDATION;

EID: 33748452832     PISSN: 10093095     EISSN: None     Source Type: Journal    
DOI: 10.1631/jzus.2006.AS0335     Document Type: Article

References (13)

1. Bowman, C.T., 1991. Chemistry of Gaseous Pollutant Formation and Destruction. In: Bartok, W., Sarofim, A.F. (Eds.), Fossil Fuel Combustion. Wiley, New York, p.215.
2. Edwards, J.R., Srivastave, R.K., Kilgroe, J.D., 2001. A study of gas-phase mercury speciation using detailed chemical kinetics. Air and Waste Manage. Assoc., 51:869-877.
3. Fu, Y., Diwekar, U.M., 2004. Cost effective environmental control technology for utilities. Advances in Environmental Research, 8(2):173-196. [doi:10.1016/S1093-0191(02)00129-6]
4. Hall, B., Lindqvist, O., Ljungstrom, E., 1990. Mercury chemistry in simulated flue gases related to waste incineration conditions. Environ. Sci. Technol., 24(1):108-111. [doi:10.1021/es00071a013]
5. ™ Process Flexibility and Multi-Pollutant Control Capability. Power Plant Air Pollutant Control Mega Symposium, Washington, D.C.
6. Kee, R.L., Rupley, F.M., Meeks, E., Miller, J.A., 1996. CHEMKIN-III: A Fortran Chemical Kinetics Package for the Analysis of Gas Phase Chemical Kinetics. SAND96-8216.
7. Kilgroe, J., Senior, C., 2003. Fundamental Science and Engineering of Mercury Control in Coal-Fired Power Plants. The Air Quality IV Conference, Arlington, VA.
8. Mallard, W.G., Westley, F., Herron, J.T., Hampson, R.F., Frizzell, D.H., 1998. NIST Chemical Kinetic Database. National Institute of Standards and Technology, USA.
9. Mamani-Paco, R., Helble, J.J., 2000. Bench Scale Examination of Mercury Oxidation under Non-Isothermal Conditions. 93rd Annual Conference of the Air and Waste Management Association, Salt Lake City, UT.
10. 2O in predicting oxidation in coal-derived systems. Environ. Sci. Technol., 35(18):3701-3706. [doi:10.1021/es010728v]
11. Senior, C.L., Sarofim, A.F., Zeng, T., Helble, J., Mamani-Paco, R., 2000. Gas-phase transformations of mercury in coal-fired power plants. Fuel Process. Technol., 63(2-3):197-213. [doi:10.1016/S0378-3820(99)00097-1]
12. Sliger, R.N., Kramlich, J.C., Marinov, N.M., 2000. Towards the development of a chemical kinetic model for the homogeneous oxidation of mercury by chlorine species. Fuel Proc. Tech., 65-66(1):423-438. [doi:10.1016/S0378-3820(99)00108-3]
13. Widmer, N.C., Cole, J.A., Seeker, W.R., Gaspar, J.A., 1998. Practical limitation of mercury speciation in simulated municipal waste incinerator flue gas. Combust. Sci. Technol., 134:315-326.