Reactions of titanium imido complexes with α-diimines: Complexation versus Ti=N/C=N bond metathesis

Journal of the Chemical Society - Dalton Transactions

Volumn , Issue 21, 1998, Pages 3623-3628

  McInnes, Jacqueline M ^a   Blake, Alexander J ^a   Mountford, Philip ^a,b  

^a UNIVERSITY OF NOTTINGHAM   (United Kingdom)

^b UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33748450709     PISSN: 03009246     EISSN: None     Source Type: Journal    
DOI: 10.1039/a806393a     Document Type: Article

References (41)

1. G. van Koten and K. Vrieze, Adv. Organomet. Chem., 1982, 21, 151.
2. K. Vrieze and G. van Koten, in Comprehensive Coordination Chemistry, ed. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon Press, Oxford, 1987; vol. 2, p. 206.
3. F. G. N. Cloke, H. C. de Lemós and A. A. Sameh, J. Chem. Soc., Chem. Commun., 1986, 1344.
4. F. G. N. Cloke, C. I. Dalby, P. J. Daff and J. C. Green, J. Chem. Soc., Dalton Trans., 1991, 181.
5. P. Scott and P. B. Hitchcock, J. Chem. Soc., Chem. Commun., 1995, 579.
6. 4OMe-4): B. Richter, J. Scholz, B. Neumüller, R. Weimann and H. Schumann, Z. Anorg. Allg. Chem., 1995, 621, 365.
7. 4: R. A. Johnson, R. B. Von Dreele and T. M. Brown, Inorg. Chem., 1984, 23, 4302.
8. N. Kaltsoyannis, J. Chem. Soc., Dalton Trans., 1996, 1583.
9. M. G. Gardiner, G. R. Hanson, M. J. Henderson, F. C. Lee and C. L. Raston, Inorg. Chem., 1994, 33, 2456.
10. J. Feldman, S. J. McLain, A. Parthasarathy, W. J. Marshall, J. C. Calabrese and S. D. Arthur, Organometallics, 1997, 16, 1514.
11. C. M. Killian, D. J. Tempel, L. K. Johnson and M. Brookhart, J. Am. Chem. Soc., 1996, 118, 11664.
12. J. March, Advanced Organic Chemistry, Wiley-Interscience, New York, 4th edn., 1992, pp. 896-897 and refs. therein.
13. P. Mountford, Chem. Commun., 1997, 2127.
14. A. J. Blake, P. E. Collier, L. H. Gade, P. Mountford, M. Schubart and I. J. Scowen, Chem. Commun., 1997, 1555.
15. A. J. Blake, S. C. Dunn, J. C. Green, N. M. Jones, A. G. Moody and P. Mountford, Chem. Commun., 1998, 1235.
16. G. I. Nikonov, A. J. Blake and P. Mountford, Inorg. Chem., 1997, 36, 1107.
17. P. J. Wilson, A. J. Blake, P. Mountford and M. Schröder, Chem. Commun., 1998, 1007.
18. P. J. Stewart, A. J. Blake and P. Mountford, Inorg. Chem., 1997, 36, 1982.
19. P. J. Stewart, A. J. Blake and P. Mountford, Organometallics, 1998, 17, 3271.
20. A. J. Blake, P. E. Collier, S. C. Dunn, W.-S. Li, P. Mountford and O. V. Shishkin, J. Chem. Soc., Dalton Trans., 1997, 1549.
21. J. M. McInnes and P. Mountford, Chem. Commun., 1998, 1669.
22. K. E. Meyer, P. J. Walsh and R. G. Bergman, J. Am. Chem. Soc., 1995, 117, 974.
23. G. K. Cantrell and T. Y. Meyer, Organometallics, 1997, 16, 5381;
24. Chem. Commun., 1997, 1551.
25. G. K. Cantrell and T. Y. Meyer, J. Am. Chem. Soc., 1998, 120, 8035.
26. For a recent review and leading references see: R. H. Grubbs and S. Chang, Tetrahedron, 1998, 54, 4413.
27. J. Alcázar, M. Begtrup and A. de la Hoz, J. Chem. Soc., Perkin Trans. 1, 1995, 2467.
28. H. tom Dieck and I. W. Renk, Chem. Ber., 1971, 104, 92.
29. H. tom Dieck, M. Svoboda and T. Greiser, Z. Naturforsch., Teil B, 1981, 36, 823.
30. L. N. Ferguson and T. C. Goodwin, J. Am. Chem. Soc., 1949, 71, 633.
31. J. Cosier and A. M. Glazer, J. Appl. Crystallogr., 1986, 19, 105.
32. A. Altomare, G. Cascarano, G. Giacovazzo, A. Guagliardi, M. C. Burla, G. Polidori and M. Camalli, J. Appl. Crystallogr., 1994, 27, 435.
33. J. R. Carruthers and D. J. Watkin, Acta Crystallogr., Sect. A, 1979, 35, 698.
34. A. C. Larson, Acta Crystallogr., 1967, 23, 664.
35. D. J. Watkin, C. K. Prout, J. R. Carruthers and P. W. Betteridge, CRYSTALS Issue 10, Chemical Crystallography Laboratory, University of Oxford, 1996.
36. D. E. Wigley, Prog. Inorg. Chem., 1994, 42, 239.
37. E. M. Shustorovich, M. A. Porai-Koshits and Y. A. Buslaev, Coord. Chem. Rev., 1975, 17, 1.
38. W. A. Nugent and J. M. Mayer, Metal-Ligand Multiple Bonds, Wiley-Interscience, New York, 1988.
39. The United Kingdom Chemical Database Service: D. A. Fletcher, R. F. McMeeking and D. Parkin, J. Chem. Inf. Comput. Sci., 1996, 36, 746.
40. K.-H. Thiele, B. Richter and B. Neumüller, Z. Anorg. Allg. Chem., 1994, 620, 1627.
41. Kinetic studies have shown that the intimate mechanism of the titanium imide complex reactions with mono-imines [eqn. (1)] is unclear (see ref. 21) and so we do not wish to speculate on the details of the imide/α-diimine mechanism here.