Molybdenum(III) chloride-tetrahydrothiophene (tht) complexes in the catalytic polymerization and cyclotrimerization of alkynes: Structures and reactivities of the possible intermediates [MoCl3(tht)2(PhC≡CR)] (R = Me or Et)

Journal of the Chemical Society - Dalton Transactions

Volumn , Issue 24, 1996, Pages 4533-4542

  Boorman, P Michael ^a   Wang, Meiping ^a   Parvez, Masood ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33748447557     PISSN: 03009246     EISSN: None     Source Type: Journal    
DOI: 10.1039/DT9960004533     Document Type: Article

References (29)

1. T. Masuda and T. Higashimura, Adv. Polym. Sci., 1987, 81, 122.
2. R. R. Schrock, Science, 1983, 219, 4580.
3. J. P. Coolman, L. S. Hegedus, J. R. Norton and R. G. Finke, Principles and Applications of Organotransition Metal Chemistry, University Science Books, Mill Valley, CA, 1987.
4. K. J. Moynihan, X. Gao, P. M. Boorman, J. F. Fait, G. K. W. Freeman, P. Thornton and D. J. Ironmonger, Inorg. Chem., 1990, 29, 1648.
5. F. A. Cotton, W. T. Hall, K. J. Kann and F. J. Karol, Macromolecules, 1981, 14, 233.
6. F. A. Cotton and W. T. Hall, Inorg. Chem., 1980, 19, 2252, 2254;
7. Inorg. Chem., 1981, 20, 17.
8. F. A. Cotton and M. Shang, Inorg. Chem., 1990, 29, 508, 2614, 2619.
9. P. M. Boorman, S. Gao, G. K. W. Freeman and J. F. Fait, J. Chem. Soc., Dalton Trans., 1991, 115.
10. Q. Feng, M. L. H. Green and P. Mountford, J. Chem. Soc., Dalton Trans., 1992, 2171;
11. S. G. Bott, D. L. Clark, M. L. H. Green and P. Mountford, J. Chem. Soc., Chem. Commun., 1989, 418.
12. R. Poli and H. D. Mui, J. Am. Chem. Soc., 1990, 112, 2446.
13. R. Poli and J. C. Gordon, Inorg. Chem., 1991, 30, 4550.
14. C. I. Simionescu and V. Percec, Prog. Polym. Sci., 1987, 8, 121.
15. C. K. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976.
16. P. Hofacker, C. Friebel and K. Dehnicke, Z. Naturforsch., Teil B, 1989, 44, 1161.
17. F. A. Cotton and R. Poli, Inorg. Chem., 1987, 26, 1514.
18. A. J. Nielson, P. D. W. Boyd, G. R. Clark, P. A. Hunt, M. B. Hursthouse, J. B. Metson, C. E. F. Rickard and P. Schwerdtfeger, J. Chem. Soc., Dalton Trans., 1995, 1153.
19. J. L. Templeton, Adv. Organomet. Chem., 1989, 29, 1.
20. A. J. Nielson, P. D. W. Boyd, G. R. Clark, T. A. Hunt, J. B. Metson, C. E. F. Rickard and P. Schwerdtfeger, Polyhedron, 1992, 11, 1419.
21. J. R. Dilworth and R. L. Richards, Inorg. Synth., 1974, 28, 33.
22. D. F. Evans, J. Chem. Soc., 1959, 2003.
23. DIFABS, N. Walker and D. Stewart, Acta Crystallogr., Sect. A, 1983, 39, 158.
24. PATTY, P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bossman, S. Garcia-Granda, R. O. Gould, J. M. M. Smits and C. Smykalla, The DIRDIF system of programs, Technical Report of the Crystallography Laboratory, University of Nijmegen, 1992.
25. DIRDIF 92; see ref. 22.
26. TEXSAN, Crystal Structure Analysis Package, Molecular Structure Corporation, 1985 and 1992.
27. D. T. Cromer and J. T. Weber, International Tables for X-Ray Crystallography, Kynoch Press, Birmingham, 1974, vol. 4, Table 2.2 A.
28. J. A. Ibers and W. C. Hamilton, Acta Crystallogr., 1964, 17, 781.
29. D. C. Creagh and W. J. McAuley, International Tables for Crystallography, ed. A. J. C. Wilson, ed, Kluwer Academic Publishers, Boston, 1992, vol. C, Table 4.2.6.8.