SiO2-TiO2 membranes by the sol-gel process

Silicon Chemistry

Volumn 3, Issue 1-2, 2006, Pages 59-64

  Mendez Vivar J ^a   Mendoza Serna, R ^b  

^a DEPARTAMENTO DE QUÍMICA   (Mexico)

^b UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

Inorganic membranes; Microporous solids; SiO2 TiO2; Sol gel

Indexed keywords

EID: 33748335688     PISSN: 15690660     EISSN: 15728994     Source Type: Journal    
DOI: 10.1007/s11201-005-9002-3     Document Type: Article

References (27)

1. Brinker, C.J., Keefer, K.D., Schaefer, D.W. & Ashley, C.S. 1982 sol-gel transition in simple silicates, J. Non-Cryst. Solids 48, 47-64.
2. Brinker, C.J. & Scherer, G.W. 1985 Sol gel glass: I. gelation and gel structure, J. Non-Cryst. Solids 70, 301-322.
3. Hsuan-Fu Yu & Shenq-Min, Wang, 2000 Effects of water content and pH on gel-derived TiO 2 -SiO 2, J. Non-Cryst. Solids 261, 260-267.
4. Brinker, C.J. & Scherer, G.W. 1990, Sol-Gel Science, The Physics and Chemistry of sol-gel Processing, San Diego CA: Academic Press, pp. 839-870.
5. De Lange, R.S.A. 1993 Microporous sol-gel Derived Ceramic Membranes for Gas Separation. Synthesis, Gas Transport and Separation Properties, Proefschrift Universiteit Twente, The Netherlands, p. 96.
6. Burggraaf, A.J. & Keiser, K. 1991 Inorganic Membranes Synthesis, Characteristics and Applications, Bhave, R.R., Ed. Van Nostrand Reinhold, N. Y., pp. 10-63.
7. Aizawa, M., Nosaka, Y. & Fujii, N. 1994 Preparation of TiO 2 -SiO 2 glass via sol-gel process containing a large amount of chlorine, J. Non-Cryst. Solids 168, 49-55.
8. Montes, M., Getton, F.P., Vong, M.S.W. & Sermon, P.A. 1997 Titania on silica. A comparison of sol-gel routes and traditional methods, J. sol-gel Sci. Tech. 8, 131-137.
9. De Lange, R.S.A., Kumar, K.-N.P., Hekkink, J.H.A., Van de Velde, G.M.H., Keiser, K., Burggraaf, A.J., Dokter, W.H., Van Garderen, H.F. & Beelen, T.P.M. 1994 Miicroporous SiO 2 an SiO 2/Mo x (M = Ti, Zr, Al) for ceramic membrane applications: A microstructural study of the sol-stage and the consolidated state, J. sol-gel Sci. Tech. 2, 489-495.
10. De Lange, R.S.A., Hekkink, J.H.A., Keiser, K. & Burggraaf, A.J. 1992 Preparation and characterization of microporous sol-gel derived ceramic membranes for gas separation applications, in: Better Ceramics Through Chemistry V, 271, Materials Research Society Symposium Proceedings, Pittsburgh, PA, pp. 505-510.
11. Méndez-Vivar, J. & Brinker, C.J. 1994 Chemical strategies for the preparation of amorphous zirconia-silica Membranes, Proceedings Third International Conference on Inorganic Membranes., Worcester, Massachusetts, Ed. Y. H. Ma, Y.H., pp. 557-560.
12. Méndez-Vivar\, J., & Brinker, C.J. 1994 Development of two approaches for preparation of zirconium silicate systems at low temperature, J. sol-gel Sci. Tech. 2, 393-397.
13. Méndez-Vivar, J., Mendoza-Serna, R., Gómez-Lara, J. & Gaviño, R. 1997 Spectroscopic Study of SiO 2 -TiO 2 sols prepared using stabilizing agents, J. sol-gel Sci. Tech. 8, 235-241.
14. Méndez-Vivar, J., Mendoza-Serna, R., Bosch, P. & Lara, V.H. 1999 Influence of Isoeugenol as a chelating agent on the structure of Si-Ti polymeric systems obtained from alkoxides, J. Non-Cryst. Solids 248, 147-158.
15. Mendoza-Serna, R., Bosch, P., Padilla, J., Lara, V.H. & Méndez-Vivar, J. 1997 Homogeneous Si-Ti and Si-Ti-Zr polymeric systems obtained from monomeric precursors, J. Non-Cryst. Solids 217, 30-40.
16. Méndez-Vivar, J. & Mendoza-Serna, R. 1998 Sintering of SiO 2 -TiO 2 Obtained by the sol-gel process from chelated Ti precursors, Scanning 20, 347-351.
17. Méndez-Vivar, J., Mendoza-Serna, R. & Valdez-Castro, L. 2001 Control of the polymerization process of multicomponent (Si, Ti, Zr) sols using chelating agents, J. Non-Cryst. Solids 288, 200-209.
18. Nijmeijer, A., Huiskes, C., Sibelt, N.G.M., Kruidhof, H. & Verweij, H. 1998, Centrifugal casting of tubular membrane supports, The American Ceramic Society Bulletin, Vol. 77, No. 4, April, 95-98.
19. Brinker, C.J., Ward, T.L., Sehgal, R., Raman, N.K., Hietala, S.L., Smith, D.M., Hua D.-W. & Headley, T.J. 1993 "Ultramicroporous" silica-based supported inorganic membranes, J. Membrane Sci., 77, 165-179.
20. Magini, M. & Cabrini, A. 1972 Programme en FORTRAN IV pour l' Analyse des Données expérimentales relatives àla Diffusion des Rayons X par des substances liquides, amorphes et microcristallisées, J. Appl. Crystallogr. 5, 14-18.
21. Duran, A., Serna, C., Fornes, V. & Fernández Navarro, J.M. 1986 Structural considerations about SiO 2 glasses prepared by sol-gel, J. Non-Cryst. Solids 82, 69-77.
22. James, P.F. 1988 The Gel to Glass transition: Chemical and microestructural evolution, J. Non-Cryst. Solids 100, 93-114.
23. Gregg, S.J. & Sing, K.S.W. 1982 Adsorption, Surface Area and Porosity, London: Academic Press. 2nd ed., p. 195.
24. Lowell, S. & Shields, J.E. 1991 Powder Surface Area and Porosity. Ed. Scarlett, B., Chapman & Hall. third ed., p. 72.
25. Ziehfreund, A. & Mair, W.F. 1996 Preparation of ultrathin supported solid electrolyte membranes for oxigen separation, Chem. Mater. 8, 2721-2729.
26. Raman, N.K., Materials Processing Issues in Organic/Inorganic sol-gel Systems, PhD Thesis, Sandia National Laboratories, Albuquerque, New Mexico, 1996, 55-76.
27. Way, J.D. & Roberts, D.L. 1992 Hollow fiber inorganic membranes for gas separations, Sep. Science Techn. 27 (1), 29-41. 29-41.