Synthesis and properties of the polythiourethanes obtained by the cationic ring-opening polymerization of cyclic thiourethanes

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 44, Issue 16, 2006, Pages 4795-4803

  Nagai, Daisuke ^a   Sato, Masato ^a   Ochiai, Bungo ^a   Endo, Takeshi ^a  

^a YAMAGATA UNIVERSITY   (Japan)

Author keywords

Block copolymerization; Cationic polymerization; Kinetics (polym.); Refractive index; Thermal properties

Indexed keywords

BLOCK COPOLYMERS; MOLECULAR WEIGHT; MONOMERS; POSITIVE IONS; PYROLYSIS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS;

3-BENZYL-1,3-OXAZOLIDINE-2-THIONE; DECOMPOSITION TEMPERATURE; MOLECULAR WEIGHT DISTRIBUTIONS; POLYMER CHAIN;

SULFUR COMPOUNDS;

EID: 33748324570     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.21557     Document Type: Article

References (21)

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17. 5 we confirmed that the endcapping reaction of the growing ends in the polymerization of BTOT with Et2NCS2 -·Na+·3H2O proceeds efficiently to produce the diethyldithiocarba mate group at the terminating end quantitatively by by MALDI-TOF mass spectroscopy analysis.
18. Because the 1H NMR spectroscopy analysis of the polymer obtained with a high feed ratio could not show the signals corresponding to the terminating end, the polymerization under a low feed ratio ([BOT]0/[BF30Et2]0 = 7.0) was performed.
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