Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst

Bioresource Technology

Volumn 98, Issue 2, 2007, Pages 416-421

  Shibasaki Kitakawa, Naomi ^a   Honda, Hiroki ^a   Kuribayashi, Homare ^a   Toda, Takuji ^a   Fukumura, Takuya ^b   Yonemoto, Toshikuni ^a  

^a TOHOKU UNIVERSITY   (Japan)

^b ICHINOSEKI NATIONAL COLLEGE OF TECHNOLOGY   (Japan)

Author keywords

Biodiesel; Continuous production; Expanded bed reactor; Ion exchange resin; Transesterification

Indexed keywords

BIODIESEL; ETHYL OLEATE; EXPANDED BED REACTORS; TRANSESTERIFICATION;

CATALYST ACTIVITY; CHEMICAL REACTORS; CROSSLINKING; ESTERIFICATION; ION EXCHANGE RESINS;

SYNTHETIC FUELS;

ALCOHOL; ANIONIC ION EXCHANGE RESIN; BIODIESEL; BIOFUEL; DIESEL FUEL; ION EXCHANGE RESIN; OLEIC ACID ETHYL ESTER; TRIOLEIN; UNCLASSIFIED DRUG;

CATALYST ACTIVITY; CHEMICAL REACTORS; CROSSLINKING; ESTERIFICATION; ION EXCHANGE RESINS; SYNTHETIC FUELS;

BIOFUEL; CATALYSIS; DIESEL; ION EXCHANGE; REGENERATION; RESIN;

ARTICLE; CATALYSIS; CATALYST; CONTINUOUS PROCESS; CROSS LINKING; DENSITY; EXPANDED BED REACTOR; PARTICLE SIZE; PRIORITY JOURNAL; REACTION ANALYSIS; REACTION TIME; TRANSESTERIFICATION;

ANIONS; CATALYSIS; ETHANOL; GASOLINE; ION EXCHANGE RESINS; TRIOLEIN;

EID: 33748324547     PISSN: 09608524     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biortech.2005.12.010     Document Type: Article

References (22)

1. Canakci M., and Van Gerpen J. Biodiesel production via acid catalysis. Trans. ASAE 42 (1999) 1203-1210
2. Canakci M., and Van Gerpen J. Biodiesel production from oils and fats with high free fatty acids. Trans. ASAE 44 (2001) 1429-1436
3. Freedman B., Pryde E.H., and Mounts T.L. Variables affecting the yields of fatty esters from transesterified vegetable oils. J. Am. Oil Chem. Soc. 61 (1984) 1638-1643
4. Freedman B., Butterfield R.O., and Pryde E.H. Transesterification kinetics of soybean oil. J. Am. Oil Chem. Soc. 63 (1986) 1375-1380
5. Fukuda H., Kondo A., and Noda H. Biodiesel fuel production by transesterification of oils. J. Biosci. Bioeng. 92 (2001) 405-416
6. Gupta M.N., and Roy I. Enzymes in organic media-forms, functions and applications. Eur. J. Biochem. 271 (2004) 2575-2583
7. Holcapek M., Jandera P., Fischer J., and Prokes B. Analytical monitoring of the production of biodiesel by high-performance liquid chromatography with various detection methods. J. Chromatogr. A 858 (1999) 13-31
8. Jaeger K.E., and Eggert T. Lipases for biotechnology. Curr. Opin. Biotechnol. 13 (2002) 390-397
9. Komers K., Stloukal R., Machek J., Skopal F., and Komersova A. Biodiesel fuel from rapeseed oil, methanol, and KOH. Analytical methods in research and production. Fett/Lipid 100 (1998) 507-512
10. Komers K., Stloukal R., Machek J., and Skopal F. Biodiesel from rapeseed oil, methanol, and KOH 3. Analysis of composition of actual reaction mixture. Eur. J. Lipid Sci. Technol. 103 (2001) 363-371
11. Komers K., Skopal F., Stloukal R., and Machek J. Kinetics and mechanism of the KOH-catalyzed methanolysis of rapeseed oil for biodiesel production. Eur. J. Lipid. Sci. Technol. 104 (2002) 728-737
12. Kusdiana D., and Saka S. Methyl esterification of free fatty acids of rapeseed oil as treated in supercritical methanol. J. Chem. Eng. Jpn. 34 (2001) 383-387
13. Kusdiana D., and Saka S. Two-step preparation for catalyst-free biodiesel fuel production-hydrolysis and methyl esterification. Appl. Biochem. Biotechnol. 113 (2004) 781-791
14. Kusdiana D., and Saka S. Effects of water on biodiesel fuel production by supercritical methanol treatment. Bioresour. Technol. 91 (2004) 289-295
15. Mazzotti M., Neri B., Gelosa D., Kruglov A., and Morbidelli M. Kinetics of liquid-phase esterification catalyzed by acidic resins. Ind. Eng. Chem. Res. 36 (1997) 3-10
16. Schuchardt U., Sercheli R., and Vargas R.M. Transesterification of vegetable oils: a review. J. Braz. Chem. Soc. 9 (1998) 199-210
17. Shah S., Sharma S., and Gupta M.N. Enzymatic transesterification for biodiesel production. Ind. J. Biochem. Biophys. 40 (2003) 392-399
18. Shimada Y., Watanabe Y., Sugihara A., and Tominaga Y. Enzymatic alcoholysis for biodiesel fuel production and application of the reaction to oil processing. J. Mol. Catal. B: Enzym. 17 (2002) 133-142
19. Vicente G., Coteron A., Martinez M., and Aracil J. Application of the factorial design of experiments and response surface methodology to optimize biodiesel production. Ind. Crops Prod. 8 (1998) 29-35
20. Vicente G., Martinez M., and Aracil J. Integrated biodiesel production: a comparison of different homogeneous catalysts systems. Bioresour. Technol. 92 (2004) 297-305
21. Warabi Y., Kusdiana D., and Saka S. Biodiesel fuel from vegetable oil by various supercritical alcohols. Appl. Biochem. Biotechnol. 113 (2004) 793-801
22. Warabi Y., Kusdiana D., and Saka S. Reactivity of triglycerides and fatty acids of rapeseed oil in supercritical alcohols. Bioresour. Technol. 91 (2004) 283-287