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Volumn 34, Issue 19, 1995, Pages 2127-2129

Porous Solids by Design: [Zn(4,4′‐bpy)2(SiF6)]n·xDMF, a Single Framework Octahedral Coordination Polymer with Large Square Channels

Author keywords

crystal engineering; hydrogen bonds; porous materials; zinc compounds

Indexed keywords


EID: 33748242606     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199521271     Document Type: Article
Times cited : (678)

References (27)
  • 10
    • 84985593703 scopus 로고    scopus 로고
    • For the purpose of this study, we define an octahedral polymer as an infinite 3D framework that is sustained by octahedral metal centers that are crosslinked by linear bifunctional ligands. We exclude infinite frameworks which consist of both octahedral metal centers and those with a different coordination geometry.
  • 15
    • 0002193270 scopus 로고
    • (a) Although Hoffmann type clathrates contain octahedral metal centers their architecture is based upon 2D μ‐cyano sustained grids:, J. L. Atwood, J. E. D. Davies, D. D. MacNicol, Academic Press, London, Chap. 2, p.
    • (1984) Inclusion Compounds , vol.1 , pp. 29
    • Iwamoto, T.1
  • 20
    • 84985552973 scopus 로고    scopus 로고
    • C‐H = 1.00 Å. Further details of the crystal struture investigation may be obtained from the Director of the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ (UK) on quoting the full journal citation.
  • 23
    • 84985593688 scopus 로고    scopus 로고
    • −3 in the corresponding dihydrate 1. The density was not determined experimentally because of the tendency of the crystals to lose solvent rapidly.
  • 24
    • 84985591962 scopus 로고    scopus 로고
    • As noted by a reviewer and revealed by Figure 1a, there is considerable distortion of the thermal ellipsoids associated with carbon atoms 2,3,5,6,2′,3′,5′ and 6′ of the 4,4′‐bipyridine ligands. This observation is consistent with slight twisting of the the pyridine moieties and either static or dynamic disorder between two orientations.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.