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Volumn 32, Issue 4, 1993, Pages 528-542

Defect Chemistry: Composition, Transport, and Reactions in the Solid State; Part II: Kinetics

Author keywords

Defect chemistry; Heterogeneous catalysis; Kinetics; Semiconductors; Solid state reactions

Indexed keywords


EID: 33748234502     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199305281     Document Type: Review
Times cited : (61)

References (69)
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    • Strictly speaking Equation (2) should, for greater accuracy, also take into account the electrochemical potential gradients of other particles (see also ref. [5]).
  • 15
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    • As explained in Part I [1] for low concentrations the chemical potential μ is a linear function of the logarithm of the concentration.
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    • The modifications to the interpretation and calculation of results from these methods that become necessary when the ionic defects can undergo internal valency changes are described in refs. [14, 17].
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    • Mat. Res. Soc. Symp. Proc. 210, Materials Research Society, Pittsburgh, p. 499
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    • J. Amer. Ceram. Soc. in press.
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    • Proc. Bilateral German‐Soviet Symp. HTSC, Karlsruhe, September
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    • Trapping effects can be treated by including trapping reactions in the diffusion process [14, 17], as well as by the inclusions of Onsager coupling terms [30].
  • 48
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    • Elementarvorgänge bei der Bildung von Metalloxyd aus Metall und Sauerstoff sowie bei verwandten Reaktionen
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    • Another extreme example is provided by the batteries used in cardiac pacemakers, in which a lithium/iodine contact forms LiI as a solid electrolyte. This results in a (self‐repairing) electrochemical cell. For a long operational life the electronic contribution to the conductivity should be negligible, since otherwise rapid self‐discharging would occur.
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    • Surfaces and interfaces are not the main topic of this article, and it would be inappropriate to go into more detail here.
  • 54
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    • ad (which correspond to the terms 1 – θ) and θ, respectively.
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    • see also the description of research in Jahrhuch der Max‐Planck‐Gesellschaft MPG, 1991, p. 364.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.