[2,3] Sigmatropic Wittig Rearrangement of Chiral Allyloxyacetaldehyde Hydrazones in the Diastereo‐ and Enantioselective Synthesis of Protected, γ,δ‐Unsaturated α‐Hydroxyaldehydes and Cyanohydrins

Angewandte Chemie International Edition in English

Volumn 33, Issue 20, 1994, Pages 2098-2100

  Enders, Dieter ^a   Backhaus, Dirk ^a   Runsink, Jan ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33748232901     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199420981     Document Type: Article

References (86)

1. Stereochemical analysis of totally stereoselective competing [1,2]- and 2,3]-Wittig rearrangements. Inversion at the lithium-bearing carbon atom
2. Asymmetric induction in reductively initiated [2,3]-Wittig and retro [1,4]-brook rearrangements of secondary carbanions
3. [2,3]1-Thia-Wittig Rearrangements Proceeding with Complete Inversion or with Partial Loss of Configuration at the Carbanionic Center
4. Asymmetric Induction and Simple Diastereoselectivity in the [2,3] Wittig Rearrangement of Ester Enolates
5. Asymmetric Induction in the Wittig-Still Rearrangement of Ethers Containing an Allylic Stereocenter – Diastereocontrol by Allylic Oxygen
6. Asymmetric Induction in the [2,3] Witting Rearrangement by Chiral Substituents in the Allyl Moiety: 1,3-Asymmetric Induction
7. (R)- and (S)-Cyanohydrins - Their Enzymatic Synthesis and Their Reactions
8. Applications of Optically Active Aryl Cyanohydrins in the Synthesis of α-Hydroxy Aldehydes, α-Hydroxy Ketones and β-Hydroxy Amines
9. Darstellung und stereoselektive Reaktionen von (R)-α-Sulfonyloxynitrilen
10. Synthese und Reaktionen optisch aktiver Cyanhydrine
11. Novel sponge-derived amino acids. 11. The entire absolute stereochemistry of the bengamides