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Volumn 32, Issue 7, 1993, Pages 1085-1087

On the Mechanism of the TCPCHFB‐Catalyzed Metathesis of 1,6‐Enyne: Evidence for Alkylidenepalladium Intermediates

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EID: 33748231046     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199310851     Document Type: Article
Times cited : (121)

References (33)
  • 6
    • 84989568332 scopus 로고
    • A reversible slippage of the TCPC unit in 2 to a cyclobutadienylpalladium(II) unit cannot be unambiguously ruled out but appears less likely. Cf.:, J. Chem. Soc. Dalton Trans., 169.
    • (1974)
    • Moseley, K.1    Maitlis, P.M.2
  • 12
    • 84989568304 scopus 로고    scopus 로고
    • This compound has been fully characterized spectrally, and the elemental composition has been established by high‐resolution mass spectrometry and/or combustion analysis.
  • 13
    • 84989568308 scopus 로고    scopus 로고
    • The valence isomer of 7, a metallacyclobutene, may also be considered as an intermediate, but does not account for the products as straightforwardly as the carbene complex.
  • 22
    • 0001160209 scopus 로고
    • Highly Functionalized Vinylcyclopropane Derivatives by Regioselective and Stereoselective Reactions of Fischer Carbene Complexes with 1,4–Disubstituted Electron–Deficient 1,3–Dienes
    • For other metals see: (a)
    • (1992) Chemische Berichte , vol.125 , pp. 2723
    • Buchert, M.1    Reissig, H.U.2
  • 30
    • 84989568353 scopus 로고    scopus 로고
    • The Chemistry of the Cyclopropyl Group pp. 809–878.
    • Salaiin, J.1
  • 31
    • 0024995762 scopus 로고
    • Vinylalkylidene metal complexes are reported to serve as dienophiles in [4+2] cycloadditions and not as the diene unit. For an excellent leading reference to this type of behavior, see,. While this report deals with Fischer‐type carbene complexes, and there are notable effects of the alkoxy group and metal ligands on the behavior of the carbene complex, this type of complex is the only current analogy. Clearly, the contrasting behavior, if any, of less stabilized vinylalkylidene metal complexes is an exciting topic for future endeavors
    • (1990) J. Am. Chem. Soc. , vol.112 , pp. 3642
    • Wulff, W.D.1    Bauta, W.E.2    Kaesler, R.W.3    Lankford, P.J.4    Miller, R.A.5    Murray, C.K.6    Yang, D.C.7


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.