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Volumn 31, Issue 3, 1992, Pages 311-313

A New Structure–Magnetism Relationship for Face‐Sharing Transition‐Metal Complexes with d3–d3 Electronic Configuration

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[No Author keywords available]

Indexed keywords


EID: 33748228883     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.199203111     Document Type: Article
Times cited : (60)

References (28)
  • 5
    • 84989585492 scopus 로고    scopus 로고
    • w = 0.062. Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, Gesellschaft für wissenschaftlich‐technische Information mbH, D‐W‐7514 Eggenstein‐Leopoldshafen 2 (FRG) on quoting the depository number CSD‐56011, the names of the authors, and the journal citation.
  • 6
    • 84989540403 scopus 로고    scopus 로고
    • Measurements of the temperature‐dependent magnetic susceptibilities (4–298 K) were conducted with a SQUID magnetometer (MPMS, Quantum Design) on powdered samples; correction for diamagnetism with Pascal's constants. In the fit of the data a paramagnetic impurity (monomeric complex with S = 3/2 ground state) was taken into account; for 2 with 0.15% impurity and for 3 with 0.2%.
  • 10
    • 84989533852 scopus 로고    scopus 로고
    • We thank Dr. Glerup (University of Copenhagen) for providing us with single crystals of 3.
  • 11
    • 84989533857 scopus 로고    scopus 로고
    • w = 0.059.
  • 23
    • 84989582694 scopus 로고    scopus 로고
    • −1.
  • 26
    • 84989582669 scopus 로고    scopus 로고
    • II) this leads to M ⃛M distances Mn 2IV > Cr 2III > V 2II, which compensates for the contraction effect.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.